A kind of saline solution etching method of suede ZNO base film
A technology of thin film corrosion and salt solution, applied in the direction of sustainable manufacturing/processing, electrical components, climate sustainability, etc., to achieve the effects of increased production and yield, significant light trapping effect, and uniform structure
Inactive Publication Date: 2011-12-07
ZHEJIANG UNIV
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Problems solved by technology
At present, there are also reports on the use of ammonium acetate and ammonium chloride solutions to form suede ZnO-based films, but there are no reports on other salt solutions as etching solutions.
Method used
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Embodiment 1
[0015] Al-doped ZnO transparent conductive films were grown by magnetron sputtering. Using ammonium phosphate solution as the etching solution, the above-mentioned Al-doped ZnO transparent conductive film was corroded for 5 minutes by using ammonium phosphate solution with a mass concentration of 5%. Such as figure 1 shown.
Embodiment 2
[0017] Al-doped ZnO transparent conductive films were grown by magnetron sputtering. Using ammonium sulfate solution as the etching solution, the above-mentioned Al-doped ZnO transparent conductive film was corroded for 1 min with ammonium sulfate solution with a mass concentration of 10%, and the textured ZnO-based film obtained was 14% at 550nm. Such as figure 2 shown.
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The invention discloses a saline solution corrosion method for a flocked ZnO-base thin film. A flocked structure is formed by corroding an intrinsic or doped ZnO, ZnMgO, ZnCdO, ZnBeO or ZnCaO thin film by adopting ammonium sulphate, ammonium nitrate or ammonium phosphate solution. The saline solution corrosion method has proper corrosion speed and is easy to operate; the texture process can be controlled well; and the prepared flocked ZnO-base thin film has high optical and electric characteristics and a remarkable light trapping effect.
Description
technical field [0001] The invention relates to an etching method for a textured ZnO-based thin film, in particular to a salt solution etching method for a textured ZnO-based thin film. Background technique [0002] The suede surface is a state of the surface topography of the film, and it is a specific manifestation of the light-trapping structure of the film. It is characterized by a relatively large surface roughness. Angle, thereby increasing the optical path of incident light in the material and increasing the absorption of light. For example, in thin-film solar cells, the transparent electrode plays a very important role in improving the conversion efficiency of the cell. Fabricating a textured transparent conductive film on a glass substrate that satisfies the light scattering characteristics can increase the short-circuit current of the cell and the incident light in the solar cell. The optical path in the battery, thereby improving the photoelectric conversion effi...
Claims
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IPC IPC(8): H01L21/02H01L31/18
CPCY02P70/50
Inventor 叶志镇王倩吕建国
Owner ZHEJIANG UNIV

