Non-ionic compound hydrate anti-agglomerant
A technology of anti-polymerization agent and hydrate, applied in the field of hydrate anti-polymerization agent, inhibiting hydrate accumulation, and non-ionic composite hydrate anti-polymerizing agent, which can solve the problems of high consumption, high cost, high toxicity, etc. Less dosage, good effect, and the effect of solving the problem of flow safety
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Embodiment 1
[0041] The antipolymerization agent provided in this example is obtained by mixing polyoxyethylene dicarboxylate type gemini nonionic surfactant with the following structure and Span-20 polyol type nonionic surfactant in a mass ratio of 1:1 .
[0042]
[0043] The oil-water emulsion of the oil-gas-water mixed transportation system is prepared from 1.0mL deionized water and 9.0mL diesel oil, that is, the volume content of water in the oil-gas-water mixed transportation system is 10% (based on the volume of water and oil The sum of the volumes is the basis for calculation), the total amount of the antipolymerization agent added is 3.0wt% (relative to the mass content of water, the same below), the composition of the gas introduced is shown in Table 1, and the test steps are similar to the visual transparent sapphire high-pressure reactor The evaluation process is the same.
[0044] The test procedure is as described above. During the whole test process, the hydrate formed a ...
Embodiment 2
[0046] The present embodiment provides a kind of antipolymerization agent, and the polyoxyethylene dicarboxylate type gemini nonionic surfactant and Span-20 polyol type nonionic surfactant that it adopts are identical with embodiment 1, both The mass ratio is 2:1, the volume content of water in the oil-gas-water mixed transportation system is 10% (based on the sum of the volumes of water and oil), and the total amount of antipolymerization agent added is 3.0% (calculated based on the volume of oil - the mass meter of water in the air-water mixed transport system).
[0047] After the test, the hydrate in the sapphire kettle formed a milky form and did not accumulate and agglomerate, indicating that the anti-aggregation agent provided in this example has the same good hydrate anti-aggregation effect as the anti-aggregation agent in Example 1.
Embodiment 3
[0049] The present embodiment provides a kind of antipolymerization agent, and the polyoxyethylene dicarboxylate type gemini nonionic surfactant and Span-20 polyol type nonionic surfactant that it adopts are identical with embodiment 1, both The mass ratio is 4:1, the volume content of water in the mixed transportation system is 10% (calculated based on the sum of the volumes of water and oil), and the total amount of antipolymerization agent added is 3.0% (calculated based on the mass of water).
[0050] After the test, the hydrate in the sapphire kettle formed a milky form and did not accumulate and agglomerate, indicating that the anti-aggregation agent provided in this example has the same good hydrate anti-aggregation effect as the anti-aggregation agent in Example 1.
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