A kind of graphene oxide anhydrous coolant for engine and preparation method thereof

A graphene and water cooling technology, applied in the direction of chemical instruments and methods, heat exchange materials, etc., can solve the problems of engine overheating performance, easy cavitation, cooling system corrosion, etc., to ease the lateral temperature gradient, improve thermal conductivity, The effect of strong thermal conductivity

Active Publication Date: 2018-04-20
四川力森特节能环保材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the coolants on the market are basically water-containing coolants (water, ethylene glycol), which have low boiling points, high freezing points, easy cavitation, and poor thermal conductivity, which are no longer sufficient to meet market demand. For example, a large amount of water-containing coolants produce The water vapor forms a steam insulation layer on the metal surface around the cylinder, which makes it impossible to conduct the heat of the engine in a timely manner, and eventually causes the engine to overheat and cause its performance to decline, and the long-term use of water-containing coolant will also cause the cooling system to appear. A series of problems such as corrosion, scale, boiling, etc., cause the cooling system to be replaced once every 1-2 years
[0004] Foreign companies believe that traditional engine coolants (water, ethylene glycol, etc.) are difficult to meet higher cooling requirements, and efficient cooling technology needs to make breakthroughs in the development of new heat transfer media with high thermal conductivity and large specific heat capacity

Method used

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  • A kind of graphene oxide anhydrous coolant for engine and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Weigh 45Kg of ethylene glycol and 48Kg of propylene glycol and stir evenly; then add 1.2Kg of silicone defoamer into it, heat and stir fully with a magnetic stirrer for about 1 hour until uniform; then add 0.5kg of tolyltriazole, 0.5kg of Benzotriazole, 0.8kg sebacic acid, 0.3kg citric acid, 0.8kg sodium hydroxide, 0.7kg phosphoric acid, 0.7kg ammonium molybdate, heated to 178°C under reflux and stirred until completely dissolved; finally added 1.5kg of graphene oxide is ultrasonically dissolved in the obtained mixed solution by an ultrasonic instrument with a frequency of 60KHZ until it is completely dissolved, and then the finished anhydrous cooling liquid of the present invention is obtained, with a freezing point of -50°C and a boiling point of 186°C.

Embodiment 2

[0023] Weigh 45Kg of ethylene glycol and 47Kg of propylene glycol and stir evenly; then add 1.2Kg of organosilicon defoamer into it, and stir fully with a magnetic stirrer for about 1 hour until uniform; then add 0.5kg of tolyltriazole, 0.5kg of benzene Triazole, 0.8kg sebacic acid, 0.6kg citric acid, 0.8kg sodium hydroxide, 0.7kg phosphoric acid, 0.7kg ammonium molybdate were heated to 180°C under reflux conditions and stirred until completely dissolved; finally added 2.2kg Graphene oxide is ultrasonically dissolved in the obtained mixed solution by an ultrasonic instrument with a frequency of 60KHZ until it is completely dissolved, and then the finished anhydrous cooling liquid of the present invention is obtained, with a freezing point of -50°C and a boiling point of 187.4°C.

Embodiment 3

[0025] Weigh 45Kg of ethylene glycol and 45Kg of propylene glycol and stir evenly; then add 1.2Kg of organosilicon defoamer to it, and stir fully with a magnetic stirrer for about 1 hour until uniform; then add 1.5kg of tolyltriazole, 0.5kg of benzene Triazole, 0.8kg sebacic acid, 0.8kg citric acid, 0.8kg sodium hydroxide, 0.7Kg phosphoric acid, 0.7Kg ammonium molybdate, heated to 183°C under reflux and stirred until completely dissolved; finally added 3kg Graphene oxide is ultrasonically dissolved in the obtained mixed solution by an ultrasonic instrument with a frequency of 60KHZ until it is completely dissolved, and the finished anhydrous cooling liquid of the present invention is obtained, with a freezing point of -50°C and a boiling point of 188.5°C.

[0026] After the product of the present invention is sent to the Chinese People's Liberation Army Oil Plant and Oil Plant Equipment Inspection and Test Center for inspection, the inspection report is as follows, and part of ...

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Abstract

The graphene oxide anhydrous cooling liquid for engine used by the present invention comprises ethylene glycol of 30 to 65% by weight, propylene glycol of 30 to 65% by weight, graphene oxide of 0.2 to 3% by weight, and The organic silicon defoamer with a percentage of 0.2-2% and the composite corrosion inhibitor with a weight percentage of 0.7-8% are mixed and stirred evenly until dissolved to obtain an anhydrous cooling liquid. The beneficial effects of the present invention are: strong thermal conductivity, freezing point lower than -50°C, boiling point as high as 188.5°C, and good corrosion resistance; the present invention uses graphene oxide with strong thermal conductivity to improve the thermal conductivity of the cooling system; organosilicon The defoamer can better prevent pitting corrosion in the cooling system; tolyltriazole and benzotriazole can well protect the copper structural parts in the engine; the neutralization buffer system composed of organic acids and their salts can effectively Regulate the pH of the cooling liquid between 7.5 and 10.0; Ammonium Phosphate-Molybdate can effectively prevent precipitation, corrosion and water pump leakage in the cooling system.

Description

technical field [0001] The invention relates to a graphene oxide water-free coolant for an engine and a preparation method thereof. Background technique [0002] The engine is the core component of the car. The power of the car and the driving of the car air conditioner are all borne by the engine. However, the efficiency of the engine with too high temperature will be reduced or even damaged, and the engine with too low temperature will increase fuel consumption. Therefore, the cooling system is the most effective guarantee to ensure the normal operation of the engine at normal operating temperature. [0003] With the continuous expansion of the engine market, the coolant used in conjunction with it has also been greatly developed. At present, the coolants on the market are basically water-containing coolants (water, ethylene glycol), which have low boiling points, high freezing points, easy cavitation, and poor thermal conductivity, which are no longer sufficient to meet ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/20
Inventor 黄方志张燕杨伟
Owner 四川力森特节能环保材料有限公司
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