Chemical stainless steel polishing solution

A chemical polishing, stainless steel technology, applied in the field of metal surface treatment, can solve the problems of long pickling time, high temperature of pickling agent, pollution of the environment, etc., to improve the surface quality, enhance the pickling effect, and improve the stability.

Inactive Publication Date: 2015-02-25
HUBEI UNIV OF EDUCATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] After the stainless steel is exposed to the air for a long time or used for a certain period of time, dust or grease will easily adhere to the surface of the stainless steel and undergo chemical changes, forming a thin and dense layer Oxide film, its main components are chromium oxide Cr2O3, nickel oxide NiO and insoluble iron chromium oxide FeO·Cr2 O3, this layer of oxide film not only affects the appearance of the product, but also affects the subsequent processing. There are mechanical methods, chemical methods and electrochemical methods to remove the oxide scale. Traditional methods are generally used in China. pickling process, commonly used pickling agents are divided into two categories: one is sulfuric acid-chromic acid series, this type of solution is stable, and has a certain polishing effect, but the chromium contained in the pickling agent seriously pollutes the environment, wastewater treatment The cost is high, one is the sulfuric acid-nitric acid series. This kind of pickling agent has a high use temperature, and the removal effect on thick scale is not ideal at room temperature. The pickling time is long, which leads to high processing costs, especially the black slag on the weld. Basically, it cannot be removed, and volatile nitrogen oxides will be produced during the polishing process, polluting the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] In this embodiment 1, prepare 1L stainless steel polishing liquid according to the following method:

[0020] Measure 400 mL of water into the reaction kettle, slowly add 50 mL of concentrated sulfuric acid while stirring, after the temperature of the solution drops to room temperature, add 30 mL of ethanol, 15 g of urea, 20 g of citric acid, and 80 mL of nitric acid, 50 mL of phosphoric acid, 120 mL of hydrogen peroxide, and 150 mL of hydrofluoric acid were stirred evenly; finally, 2 g of hexamethylenetetramine, 0.5 g of sodium dodecylbenzenesulfonate and the rest of water were added to the reactor and stirred evenly to obtain Colorless and clear stainless steel chemical polishing solution.

Embodiment 2

[0022] In this embodiment 2, prepare 1L stainless steel polishing liquid according to the following method:

[0023] Measure 400 mL of water into the reaction kettle, slowly add 65 mL of concentrated sulfuric acid according to the formula while stirring, and after the temperature of the solution drops to room temperature, add 20 mL of ethanol, 10 g of urea, 30 g of citric acid, and 100 mL of nitric acid, 65 mL of phosphoric acid, 80 mL of hydrogen peroxide, and 120 mL of hydrofluoric acid were stirred evenly; finally, 4 g of hexamethylenetetramine, 1 g of sodium dodecylbenzenesulfonate and the rest of water were added to the reaction kettle and stirred Evenly, a colorless and clear stainless steel chemical polishing solution is obtained.

Embodiment 3

[0025] In this embodiment 3, prepare 1L stainless steel polishing liquid according to the following method:

[0026] Measure 400mL of water into the reaction kettle, slowly add 80mL of concentrated sulfuric acid according to the recipe while stirring, and after the temperature of the solution drops to room temperature, add 10mL of ethanol, 5g of urea, 40g of citric acid, and 120mL of Nitric acid, 80 mL of phosphoric acid, 50 mL of hydrogen peroxide, and 50 mL of hydrofluoric acid were stirred evenly; finally, 6 g of hexamethylenetetramine, 2 g of sodium dodecylbenzenesulfonate and the rest of water were added to the reactor and stirred evenly , to obtain a colorless and clear stainless steel chemical polishing solution.

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Abstract

The invention discloses a chemical stainless steel polishing solution which comprises the following components in content: 80mL/L to 120mL/L of 68% nitric acid, 50mL/L to 150mL/L of 40% hydrofluoric acid, 50mL/L to 120mL/L of 30% hydrogen peroxide, 50mL/L to 80mL/L of 85% phosphoric acid, 50mL/L to 80mL/L of 98% concentrated sulfuric acid, 10mL/L to 30mL/L of 95% ethanol, 5g/L to 15g/L of urea, 20g/L to 40g/L of a brightening agent, 0.5g/L to 2g/L of a fog inhibitor and 2g/L to 6g/L of a corrosion inhibitor. The chemical polishing solution is stable in polishing speed; a processed stainless steel workpiece is flat in surface, bright, free of dust, also stable in performance, capable of being stored for a long time and low in production cost; during polishing, irritant acidic gas is small in volatility.

Description

technical field [0001] The invention relates to the field of metal surface treatment, in particular to a stainless steel chemical polishing liquid. Background technique [0002] After the stainless steel is exposed to the air for a long time or used for a certain period of time, dust or grease will easily adhere to the surface of the stainless steel and undergo chemical changes, forming a thin and dense oxide film, the main component of which is chromium oxide Cr 2 o 3 , nickel oxide NiO and insoluble iron chromium oxide FeO Cr 2 o 3 , this layer of oxide film not only affects the appearance of the product, but also affects the subsequent processing. There are mechanical, chemical and electrochemical methods to remove the oxide scale. The traditional pickling process is generally used in China, and pickling agents are commonly used. Divided into two categories: one is sulfuric acid-chromic acid series, this kind of solution is stable and has a certain polishing effect, bu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F3/06
Inventor 吴田刘琼曾国平马晓玲陈功轩
Owner HUBEI UNIV OF EDUCATION
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