Water-based first coating for tire bead steel wire plating aftertreatment
A bead wire and substrate technology, applied in coating, liquid chemical plating, metal material coating process and other directions, can solve the problem of shortening tire service life, affecting tire performance, and weak adhesion between bead wire substrate and rubber and other problems, to achieve the effect of enhancing the bonding strength and increasing the adhesion rate
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Embodiment 1
[0013] Example 1: A water base coating solution for post-plating treatment of bead wires, consisting of 0.7% N-β (aminoethyl)-γ-aminopropylmethyldimethoxysilane, 0.1 % bis(triethoxysilylpropyl) tetrasulfide, 0.16% bis(triethoxysilylpropyl) disulfide, 0.04% 3-thiooctanoyl-1-propyl trisulfide Composed of ethoxysilane, 60% methanol, 30% ethanol, and the rest of water, use a 6cm cotton thread soaked in the above water-based coating solution, apply it on the surface of a 0.95mm tinned bronze bead wire, and one end of the silane coupling agent The hydrolyzed group undergoes hydrolysis and reacts with the steel wire matrix to combine, and the organic group at the other end can react with the organic components in the post-treatment process to effectively connect the inorganic metal and the organic resin; compared with the single-coated organic coating liquid, First apply the water-based coating solution and then apply the organic coating solution, the adhesion between the steel wire ...
Embodiment 2
[0014] Example 2: A water-based coating solution for post-plating treatment of bead wires, consisting of 0.8% N-β (aminoethyl)-γ-aminopropylmethyldimethoxysilane, 0.15 % of bis(triethoxysilylpropyl) disulfide, 0.1% of 3-thiooctanoyl-1-propyltriethoxysilane, 60% of methanol, 25% of ethanol, and the balance of water Composition: use 8cm cotton thread soaked in the above water-based coating solution, and apply it on the surface of 1.20mm tinned bronze bead wire. The group can react with the organic components in the post-treatment process, effectively connecting the inorganic metal and the organic resin; compared with the single-coating organic coating solution, the water base coating solution is first coated and then the organic coating solution, and the steel wire and the organic coating solution The adhesion between rubber and the adhesive rate after bonding are significantly improved. After this treatment, the adhesive force between the steel wire and rubber is greater than 1...
Embodiment 3
[0015] Embodiment three: see figure 1 Shown, a kind of post-plating coating treatment method of bead steel wire comprises the steps:
[0016] ① Select a high-strength plated bead wire with a tin bronze coating weight of 0.39-0.58g / kg, a tin content of 4-10%, and a diameter of 1.30mm;
[0017] ② Rinse with cold water to remove the impurity ions remaining on the surface of the steel wire in the previous process, and dry the steel wire in an oven at 160°C;
[0018] ③ Smear the steel wire obtained in step ② with a 5cm cotton thread and apply the water base coating solution for the post-plating treatment of bead steel wires according to the present invention. The water base coating solution contains N-β (aminoethyl)-γ-ammonia with a mass fraction of 0.6%. Propylmethyldimethoxysilane, 0.05% bis(triethoxysilylpropyl) tetrasulfide, 0.15% 3-thiooctanoyl-1-propyltriethoxysilane, 60% Methanol, 28% ethanol, the balance is water, and then dried by cold air;
[0019] 4. smear organic coa...
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