Novel material for repairing heavy metal Cr-Pb-Cd contaminated soil as well as preparation method and using method of novel material
A technology of cr-pb-cd and polluted soil, which is applied to new materials for repairing heavy metal Cr-Pb-Cd polluted soil and its preparation, and the field of heavy metal pollution control, and can solve complex preparation process, secondary pollution, soil compaction, etc. question
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[0052] Step 1 Preparation of modified carbon nanotubes
[0053] Take carbon nanotubes, 65% concentrated nitric acid and 0.5 mol / L potassium permanganate and mix them evenly in a ratio of 1:2:5 in mass parts, let it stand for cooling, and oxidize the cooled material at 90°C After 2 h, centrifuge, filter and cool, wash and centrifuge repeatedly with deionized water until the pH of the supernatant is neutral, dry at 80°C to constant weight, grind, and pass through a 200-mesh sieve to obtain modified carbon nanotubes. The modified carbon nanotubes are stored in a desiccator.
[0054] Step 2 Preparation of modified natural zeolite and montmorillonite
[0055] Dry natural zeolite and montmorillonite naturally, grind them into powder with a mortar, and sieve through a 200-mesh sieve to obtain pretreated products of zeolite and montmorillonite. Added concentration is 3 mol / L HNO 3 solution (pH=4.0), the solid-to-liquid ratio was 1:3, the temperature was controlled at 80°C, soaked a...
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