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4,6-dinitrobenzene triazole-1-oxide guanylurea salt compound

A technology of dinitrobenzene and vicinal triazole is applied in the field of 4,6-dinitrobenzotriazole-1-oxide amidine urea salt compound, and can solve the problems of low nitrogen content and low thermal decomposition point.

Inactive Publication Date: 2015-12-30
XIAN MODERN CHEM RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the nitrogen content and thermal decomposition point of this compound are low

Method used

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  • 4,6-dinitrobenzene triazole-1-oxide guanylurea salt compound
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  • 4,6-dinitrobenzene triazole-1-oxide guanylurea salt compound

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Embodiment 1

[0021] (1) 4,6-Dinitrobenzotriazole-1-oxide potassium salt

[0022] 20°C, add 1.0g (4.44mmol) of 4,6-dinitrobenzotriazole-1-oxide into 80mL of ethanol, heat up to 40°C, dropwise add 0.25g (4.46mmol) of hydroxide Aqueous potassium hydroxide solution composed of potassium and 0.4g (22.2mmol) water, reacted at 40°C for 2h after addition, then removed the solvent with a rotary evaporator, washed the remaining solid with anhydrous ether, and dried to obtain 4,6-dinitrobenzene Paratriazole-1-oxide potassium salt 1.0 g, yield 85.5%.

[0023] Structure Identification:

[0024] NMR spectrum: 1 HNMR (DMSO-d 6 ,500MHz), δ: 9.096(1H,CH),8.880(1H,CH);

[0025] 13 CNMR (DMSO-d 6 ,125MHz), δ:144.830,137.430,136.783,130.260,117.535,115.295;

[0026] Elemental analysis: Molecular formula: C 6 h 2 N 5 o 5 K

[0027] Theoretical value: C27.38, H0.77, N26.61;

[0028] Measured values: C27.41, H0.83, N26.32.

[0029] It was confirmed that the substance obtained by the above-mentioned...

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Abstract

The invention discloses a 4,6-dinitrobenzene triazole-1-oxide guanylurea salt compound. A structural formula is as shown in (I) in the specification. The 4,6-dinitrobenzene triazole-1-oxide guanylurea salt compound is mainly applied to a composite explosive and a solid propellant.

Description

technical field [0001] The invention relates to a 4,6-dinitrobenzotriazole-1-oxide amidinourea salt compound, which belongs to the field of energetic materials. technical background [0002] Energetic ionic salts are a new class of energetic materials with unique properties developed in recent years. They have advantages that non-ionic molecules do not have, such as good thermal stability, high density and energy, and low vulnerability. In recent years, benzotriazole-1-oxide energetic compounds have become a research hotspot of energetic materials due to their insensitivity. For example, T.H.Klapotke, CarolinPluger, Muhamed Suceska. Zwitterionicexplosivesbasedon4,6-dinitrobenzotriazol-3-ium-1-oxide. Newtrendsinresearchofenergeticmaterials, CzechRepublic, 2014, 754-768 discloses that 4,6-dinitrobenzotriazol-3-ium-1-oxide The structure of the compound and its partial physicochemical detonation performance, its structure is shown in (II): [0003] [0004] The nitrogen con...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D249/18
CPCC07D249/18
Inventor 霍欢王伯周毕福强李祥志董军翟连杰李亚南贾思媛王锡杰罗义芬
Owner XIAN MODERN CHEM RES INST