Novel azocyclotin
A new type of triazolin technology, which is applied in the field of pesticide manufacturing, can solve the problems of citrus phytotoxicity and citrus phytotoxicity when triazolin is used, and achieve the effect of improving bactericidal ability, temperature sensitivity and resistance
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Embodiment 1
[0011] A new type of triazotin, including flufenuron, triazotin and auxiliary agents, flufenuron and triazotin are mixed according to the ratio of 1:1.5, and the content of each component of triazotin is chlorocyclohexane 200kg / t, 1,2,4-triazole 100 kg / t, benzimidazole 800 kg / t, tin 2500kg / t and chlorine gas 150kg / t, the content of each component of the auxiliary agent is pine resin mixture 10 kg / t, machine pumping Emulsion 5kg / t, lime sulfur 1kg / t. Lime-sulfur mixture is prepared by mixing quicklime and sulfur at a ratio of 5:1, and turpentine mixture is prepared from rosin, caustic soda, and water at a ratio of 4:3:8. The preparation process of tin triazolium is the reaction of tin tetrachloride with cyclohexane chloride, then chlorination, alkalization, and finally the reaction with 1,2,4-triazole.
Embodiment 2
[0013] The present invention includes flufenuron, triazotin and auxiliary agents, flufenuron and triazotin are mixed according to the ratio of 1:1.5, and the content of each component of triazotin is chlorocyclohexane 250kg / t, 1,2 , 110 kg / t of 4-triazole, 800 kg / t of benzimidazole, 3000 kg / t of tin and 160 kg / t of chlorine; / t, lime sulfur mixture 3kg / t. Lime-sulfur mixture is prepared by mixing quicklime and sulfur at a ratio of 5:1, and turpentine mixture is prepared from rosin, caustic soda, and water at a ratio of 4:3:8. The preparation process of tin triazolium is the reaction of tin tetrachloride with cyclohexane chloride, then chlorination, alkalization, and finally the reaction with 1,2,4-triazole.
Embodiment 3
[0015] The present invention includes flufenuron, triazotin and auxiliary agent, flufenuron and triazotin are mixed according to the ratio of 1:1.5; the content of each component of triazotin is chlorocyclohexane 280kg / t, 1,2 , 115 kg / t of 4-triazole, 800 kg / t of benzimidazole, 3200 kg / t of tin and 165 kg / t of chlorine gas; the content of each component of the auxiliary agent is 10 kg / t of turpentine mixture and 7kg / t of machine-pumped emulsion , Lime sulfur mixture 4kg / t. Lime-sulfur mixture is prepared by mixing quicklime and sulfur at a ratio of 5:1, and turpentine mixture is prepared from rosin, caustic soda, and water at a ratio of 4:3:8. The preparation process of tin triazolium is the reaction of tin tetrachloride with cyclohexane chloride, then chlorination, alkalization, and finally the reaction with 1,2,4-triazole.
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