Method for inhibiting plants from absorbing soil fluorine by using activated sludge modified clay mineral

A clay mineral and activated sludge technology, applied in the field of soil pollution remediation, can solve problems such as secondary soil pollution, achieve low cost, reduce the risk of high concentration of pollutants, and stabilize the molecular structure.

Active Publication Date: 2018-02-02
ZHEJIANG NORMAL UNIV XINGZHI COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005]The above method uses exogenous industrial substances, and extra care must be taken during the operation, as there is a certain risk of secondary pollution to the soil
In addition, the remediation of fluorine-contaminated soil is mainly aimed at water-soluble fluorine. Although the absorption of nutrients in the soil by plant roots is somewhat related to the water-soluble state, as a biological transport method, the length of the molecular chain, molecular weight, surface base of the absorption object Factors such as the nature of the group have a great influence on the
[0006]Therefore, it is of great significance to remediate soil fluorine pollution and reduce its impact on human health. However, there are certain limitations in the current remediation technology, and the development of inhibition of plants absorbing soil The method of fluorine has feasibility and application prospect

Method used

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  • Method for inhibiting plants from absorbing soil fluorine by using activated sludge modified clay mineral
  • Method for inhibiting plants from absorbing soil fluorine by using activated sludge modified clay mineral
  • Method for inhibiting plants from absorbing soil fluorine by using activated sludge modified clay mineral

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Effect test

Embodiment 1

[0029] A kind of activated sludge modification clay mineral suppresses the method for plant absorbing soil fluorine, comprises the steps:

[0030] ⑴ Measure 10m of clean water 3 Put it into the pool, add 2300g of glucose, 120g of general calcium, and 430g of urea, stir well to dissolve it;

[0031] ⑵ Add 13kg of activated sludge (calculated as dry matter) in the biochemical pool of the urban sewage treatment plant into the pool as bacteria, 120kg of clay minerals, and stir evenly; the aeration rate per unit area is 3.8m 3 / h fan, continuous aeration for 6 hours at intervals of 2.5 hours, and stop aeration after 5 days;

[0032] (3) Add 4.3kg of calcium chloride to the pool and stir evenly, let it settle,

[0033] (4) After collecting the sediment, wash it with water three times, and treat it at 120°C for 25 minutes to obtain activated sludge modified clay minerals;

[0034] (5) Add the activated sludge modified clay mineral to a thickness of about 1.5cm in the 15cm cultivat...

Embodiment 2

[0038] ⑴ Measure 10m of clean water 3 Put it into the pool, add 2800g of glucose, 100g of general calcium, and 380g of urea, stir well to dissolve it;

[0039] (2) Then add 12kg of activated sludge (in terms of dry matter) in the biochemical tank of the urban sewage treatment plant as bacteria, 130kg of clay minerals, and stir evenly; the aeration rate per unit area is 3.5m 3 / h fan, continuous aeration for 8 hours every 2 hours, after 4 days, stop aeration;

[0040] (3) Add 3.5kg of calcium chloride and stir evenly, let stand to settle;

[0041] (4) Then collect the sediment, wash it twice with water, and treat it at 120°C for 30 minutes to obtain activated sludge modified clay minerals;

[0042] (5) Add the activated sludge modified clay mineral to the 20cm of the cultivation layer of the fluorine-polluted soil, so that its volume accounts for about 15% of the soil volume of the cultivation layer, turn the soil and mix it, and plant crops.

[0043] In addition, the activate...

Embodiment 3

[0046] ⑴ Measure 10m of clean water 3 Put it into the pool, add glucose 2100g, general calcium 95g, urea 320g, stir well to dissolve it;

[0047] (2) Then add 11kg of activated sludge (in terms of dry matter) in the biochemical tank of the urban sewage treatment plant as bacteria, 150kg of clay minerals, and stir evenly; the aeration rate per unit area is 4.0m 3 / h fan, continuous aeration for 7 hours every 3 hours, and stop aeration after 3 days;

[0048] (3) Add 4kg of calcium chloride and stir evenly, let it stand for precipitation;

[0049] (4) After collecting the sediment, wash it with water three times, and treat it at 120°C for 20 minutes to obtain activated sludge modified clay minerals;

[0050] (5) Add the activated sludge modified clay minerals within 15cm of the cultivated layer of uncontaminated soil, so that its volume accounts for about 13% of the soil volume of the cultivated layer, mix the soil, plant vegetables and fruits, and water with fluorine-contamina...

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Abstract

The invention relates to a method for inhibiting plants from absorbing soil fluorine by using activated sludge modified clay mineral. According to the technical scheme, the method comprises the following steps of (1) measuring and putting clear water into a container, adding a certain amount of glucose, calcium superphosphate and urea, and fully stirring the mixture for dissolution; (2) collectingactivated sludge in a biochemical pond of a municipal sewage treatment plant to serve as a strain, putting the activated sludge into the container in the step (1), adding clay mineral and stirring the mixture uniformly, and then carrying out intermittent aeration; (3) after aeration is finished, adding calcium chloride and stirring the mixture uniformly, and standing and precipitating; (4) aftercollecting precipitate obtained through separation in the step (3), rinsing the precipitate with clear water and then carrying out high-temperature treatment to obtain the activated sludge modified clay mineral; and (5) adding the activated sludge modified clay mineral to a tillage layer of fluorine-polluted soil, turning and mixing the soil, and then carrying out conventional cultivation of the plants. According to the method, operation is simple, cost is low, and the fluorine element in the soil can be fixed in the spatial structure of the clay mineral, so that the absorption of the plants is effectively inhibited.

Description

technical field [0001] The invention belongs to the technical field of soil pollution remediation, in particular to a method for inhibiting plants from absorbing soil fluorine by modifying clay minerals with activated silt. Background technique [0002] Although fluorine (F) is one of the trace elements in the normal physiological activities of the body, excessive intake of humans can cause fluorosis symptoms such as skeletal fluorosis, dental fluorosis, and brain damage, which is called endemic fluorosis, commonly known as ground fluorosis. Fluorosis. The disease is a typical geochemical disease and affects many countries and regions in the world. my country is a country with high distribution of endemic fluorosis. Endemic fluorosis is usually divided into four categories: drinking water type, food type, coal burning type and mixed type. Endemic fluorosis caused by soil fluorine pollution is a mixed type, that is, soil fluorine pollution can contaminate shallow groundwate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B09C1/00B09C1/02B09C1/08B09C1/10C09K17/40
CPCC09K17/40B09C1/00B09C1/02B09C1/08B09C1/10B09C2101/00Y02W10/10
Inventor 陈寒松李小忠郑绍成李铭红郑孝华吴婷
Owner ZHEJIANG NORMAL UNIV XINGZHI COLLEGE
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