Hydrotalcite intercalation chloride ion probe modified triazole corrosion inhibitor compound containing Schiff base and application thereof

A technology of Schiff base triazole and chloride ion probes, which is applied in the field of rust inhibitors, can solve the problems of weakening the application stability and long-term durability of rust inhibitors, and the performance of high efficiency is only on paper, and achieves a comprehensive The effect of low application cost, excellent rust resistance and good environmental compatibility

Inactive Publication Date: 2018-05-04
INST OF OCEANOLOGY - CHINESE ACAD OF SCI
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  • Abstract
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  • Claims
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Problems solved by technology

[0003] The traditional research and development ideas of rust inhibitors are limited to the isolation and protection of the surface of steel bars, but have not yet focused on the treatment of corrosive media and the adaptation to the concrete body environment, which seriously weakens the application stability and long-term durability of rust inhibitors. , so that the performance of high efficiency is on paper

Method used

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  • Hydrotalcite intercalation chloride ion probe modified triazole corrosion inhibitor compound containing Schiff base and application thereof

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Effect test

Embodiment

[0037] Preparation of Triazole Corrosion Inhibitor Complex Modified by Hydrotalcite Intercalation Chloride Ion Probe

[0038] The first step: prepare the triazole precursor modified by chloride ion probe.

[0039] Press p-aminobenzoic acid in [N + -H...O] molar stoichiometric ratio of hydrogen bond formation by adding 1-(2"-nitrophenyl)methanimino-2-mercapto-5-(1'-(1',2',4'-tri Azole))methylene 1,3,4-triazole polyether rust inhibitor aqueous solution (2.4×10 -3 mol / L), using 2.2 equivalents of HBr for protonation titration to prepare the intercalation precursor of triazole rust inhibitor containing Schiff base modified by chloride ion probe.

[0040] The second step: the reaction formula of synthesizing zinc-aluminum hydrotalcite is as follows:

[0041] Zn(NO 3 ) 2 ·6H 2 O+2NaOH=Zn(OH) 2 ↓+2NaNO 3 +6H 2 O (1)

[0042] Al(NO 3 ) 3 9H 2 O+3NaOH=Al(OH) 3 ↓+3NaNO 3 +9H 2 O (2)

[0043] 0.67Zn(OH) 2 +0.33Al(OH) 3 +mH 2 O+0.165Na 2 CO 3

[0044] =[Zn 0.67 al ...

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Abstract

The invention relates to a corrosion inhibitor, in particular to a hydrotalcite intercalation chloride ion probe modified triazole corrosion inhibitor compound containing Schiff base and application thereof. Through chloride ion probe modification and intercalation assembly, a chloride ion trigger switch which can regulate and control release of a triazole corrosion inhibitor containing the Schiffbase is embedded between zinc-aluminum hydrotalcite layers, and the compound is formed. By adopting the corrosion inhibitor compound provided by the invention, mass production can be realized, release responding to a corrosion environment and repairing of corroded carbon steel can be realized, and the corrosion inhibitor compound has long-term protective effect and can effectively carry out corrosion protection on the carbon steel, so that the corrosion inhibitor compound provided by the invention has obvious application value and a broad market prospect.

Description

technical field [0001] The invention relates to a rust inhibitor, in particular to a hydrotalcite intercalation chloride ion probe modified compound containing a Schiff base triazole rust inhibitor and application thereof. Background technique [0002] Reinforced concrete is the main material of coastal and offshore engineering construction. Under the marine corrosion environment, the corrosion of steel bars caused by the diffusion and penetration of high-concentration chloride ions is the crux of the degradation of concrete materials and structural performance. The application of organic migrating corrosion inhibitor (Migrating Corrosion Inhibitor, MCI) as a simple, economical and efficient steel anticorrosion material is the first choice for isolating chloride ion corrosion. [0003] The traditional research and development ideas of rust inhibitors are limited to the isolation and protection of the surface of steel bars, but have not yet focused on the treatment of corrosi...

Claims

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Application Information

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IPC IPC(8): C04B24/16C01G9/00C04B103/61
CPCC01G9/006C04B40/0046C04B2103/61C04B22/10C04B24/12C04B22/122C04B24/16
Inventor 田惠文李伟华刘昂侯保荣
Owner INST OF OCEANOLOGY - CHINESE ACAD OF SCI
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