Self-healing type super-amphiphobic and photocatalytic double self-cleaning coating and method for preparing same
A self-cleaning coating, super-amphiphobic technology, applied in coatings, anti-fouling/underwater coatings, paints containing biocide, etc., can solve the problems of low coating life, narrow coating application surface, and self-cleaning ability Ineffectiveness and other problems, to achieve the effect of simple preparation method, excellent super oleophobic performance, and wide application
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Embodiment 1
[0038] In this embodiment, the self-healing super-double phobic and photocatalytic dual self-cleaning coating is formed by coating the surface of cotton fabric with a mixed solution containing F-POSS and photocatalytic particles; the photocatalytic particles are titanium dioxide particles, and the photocatalytic particles are combined with The quality ratio of F-POSS is 1;
[0039] F-POSS is prepared from fluorine-containing siloxane as a precursor; fluorine-containing siloxane is 1H,1H,2H,2H-tridecafluorooctyltriethoxysilane;
[0040] The mixed solution is formed by dispersing F-POSS and titanium dioxide photocatalytic particles in a fluorine-containing solvent, which also contains other micro / nano particles; the mass ratio of other micro / nano particles to F-POSS is 1.
[0041] Other micro / nano particles are polytetrafluoroethylene particles.
[0042] The fluorine-containing solvent is DuPont Capstone ST-110 fluorocarbon surfactant.
[0043] The preparation method of the self-healing ...
Embodiment 2
[0054] In this embodiment, the self-healing super-double phobic and photocatalytic double self-cleaning coating is formed by coating the surface of polyester fabric with a mixed solution containing F-POSS and photocatalytic particles; the photocatalytic particles are titanium dioxide particles, and the photocatalytic particles are combined with The quality ratio of F-POSS is 2;
[0055] F-POSS is prepared from fluorine-containing siloxane as a precursor; fluorine-containing siloxane is 1H, 1H, 2H, 2H-heptadecafluorodecyltrimethoxysilane;
[0056] The mixed solution is formed by dispersing F-POSS and titanium dioxide photocatalytic particles in a fluorine-containing solvent;
[0057] The fluorine-containing solvent is DuPont Capstone ST-300 fluorocarbon surfactant.
[0058] The preparation method of the self-healing super-double phobic and photocatalytic double self-cleaning coating is as follows:
[0059] Step 1. Prepare F-POSS:
[0060] Dissolve fluorine-containing siloxane 1H, 1H, 2H,...
Embodiment 3
[0069] In this embodiment, the self-healing super-double phobic and photocatalytic double self-cleaning coating is formed by coating a mixed solution containing F-POSS and photocatalytic particles on the glass surface; the photocatalytic particles are titanium dioxide particles, and the photocatalytic particles are combined with F-POSS. -The quality ratio of POSS is 4;
[0070] F-POSS is prepared from fluorine-containing siloxane as a precursor; fluorine-containing siloxane is 1H, 1H, 2H, 2H-heptadecafluorodecyltrimethoxysilane;
[0071] The mixed solution is formed by dispersing F-POSS and titanium dioxide photocatalytic particles in a fluorine-containing solvent, which also contains other micro / nano particles; the mass ratio of other micro / nano particles to F-POSS is 5.
[0072] Other micro / nano particles are polytetrafluoroethylene particles.
[0073] The fluorine-containing solvent is 2H,3H-perfluoropentane.
[0074] The preparation method of the self-healing super-double phobic an...
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