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A self-healing superamphiphobic and photocatalytic dual self-cleaning coating and its preparation method

A self-cleaning coating, super-amphiphobic technology, applied in coatings, antifouling/underwater coatings, paints containing biocides, etc., can solve the problem of low coating life, narrow coating application area, self-cleaning ability problems such as failure, to achieve the effect of simple and easy preparation method, excellent superoleophobic performance, and wide application

Active Publication Date: 2020-09-15
SUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Although in recent years, there have been the above-mentioned and other few researches on superhydrophobic and photocatalytic dual self-cleaning coatings, but at present this kind of coating has the following problems: 1) it is only superhydrophobic, that is, it only has waterproof effect, and No protection against oily liquids
Because photocatalytic surfaces are usually only able to decompose trace amounts of organic pollutants that are in close contact with the surface, if such superhydrophobic and photocatalytic dual self-cleaning coatings are contaminated with a large amount of oil, the self-cleaning ability will fail
2) While the photocatalytic effect removes surface organic pollutants, it will also cause the gradual degradation of low surface energy substances that contribute to superhydrophobic properties, resulting in a decline in superhydrophobic properties or complete failure
At present, the above problems have not been well resolved in the existing research work of superhydrophobic and photocatalytic dual self-cleaning coatings, resulting in narrow application of such coatings and low coating life

Method used

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  • A self-healing superamphiphobic and photocatalytic dual self-cleaning coating and its preparation method
  • A self-healing superamphiphobic and photocatalytic dual self-cleaning coating and its preparation method
  • A self-healing superamphiphobic and photocatalytic dual self-cleaning coating and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] In this example, the self-healing superamphiphobic and photocatalytic double self-cleaning coating is formed by coating the surface of cotton fabric with a mixed solution containing F-POSS and photocatalytic particles; the photocatalytic particles are titanium dioxide particles, and the photocatalytic particles are mixed with The mass ratio of F-POSS is 1;

[0039] F-POSS is prepared from fluorine-containing siloxane as a precursor; fluorine-containing siloxane is 1H, 1H, 2H, 2H-tridecafluorooctyltriethoxysilane;

[0040] The mixed solution is formed by dispersing F-POSS and titanium dioxide photocatalytic particles in a fluorine-containing solvent, which also contains other micro / nano particles; the mass ratio of other micro / nano particles to F-POSS is 1.

[0041] Other micro / nano particles are polytetrafluoroethylene particles.

[0042] The fluorine-containing solvent is DuPont Capstone ST-110 fluorocarbon surfactant.

[0043] The preparation method of the self-healin...

Embodiment 2

[0054] In this example, the self-healing superamphiphobic and photocatalytic double self-cleaning coating is formed by coating the surface of polyester fabric with a mixed solution containing F-POSS and photocatalytic particles; the photocatalytic particles are titanium dioxide particles, and the photocatalytic particles are mixed with The mass ratio of F-POSS is 2;

[0055] F-POSS is prepared from fluorine-containing siloxane as a precursor; fluorine-containing siloxane is 1H, 1H, 2H, 2H-heptadecafluorodecyltrimethoxysilane;

[0056] The mixed solution is formed by dispersing F-POSS and titanium dioxide photocatalytic particles in a fluorine-containing solvent;

[0057] The fluorine-containing solvent is DuPont Capstone ST-300 fluorocarbon surfactant.

[0058] The preparation method of the self-healing superamphiphobic and photocatalytic dual self-cleaning coating is as follows:

[0059] Step 1. Preparation of F-POSS:

[0060] Dissolve the fluorine-containing silicone 1H, ...

Embodiment 3

[0069] In this example, the self-healing superamphiphobic and photocatalytic double self-cleaning coating is formed by coating the glass surface with a mixed solution containing F-POSS and photocatalytic particles; the photocatalytic particles are titanium dioxide particles, and the photocatalytic particles are combined with F-POSS - The mass ratio of POSS is 4;

[0070] F-POSS is prepared from fluorine-containing siloxane as a precursor; fluorine-containing siloxane is 1H, 1H, 2H, 2H-heptadecafluorodecyltrimethoxysilane;

[0071] The mixed solution is formed by dispersing F-POSS and titanium dioxide photocatalytic particles in a fluorine-containing solvent, which also contains other micro / nano particles; the mass ratio of other micro / nano particles to F-POSS is 5.

[0072] Other micro / nano particles are polytetrafluoroethylene particles.

[0073] The fluorinated solvent is 2H,3H-perfluoropentane.

[0074] The preparation method of the self-healing superamphiphobic and photo...

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Abstract

The invention discloses a self-healing type super-amphiphobic and photocatalytic double self-cleaning coating and a method for preparing the same. Mixed solution with fluorine-polyhedral oligomeric silsesquioxane (F-POSS) and photocatalysis particles is coated on the surfaces of base materials to form the self-healing type super-amphiphobic and photocatalytic double self-cleaning coating. The self-healing type super-amphiphobic and photocatalytic double self-cleaning coating and the method have the advantages that the self-healing type super-amphiphobic and photocatalytic double self-cleaningcoating has super-hydrophobic and super-oleophobic super-amphiphobic performance, is capable of photocatalytically degrading organic pollutants adhered on the surfaces of the self-healing type super-amphiphobic and photocatalytic double self-cleaning coating, can be self-healed and can be placed at the room temperature or can be appropriately heated, and accordingly degradation of the super-amphiphobic performance due to long-time illumination can be repaired; the self-healing type super-amphiphobic and photocatalytic double self-cleaning coating is applicable to the surfaces of the base materials for glass, wood, building external walls, diversified textiles and the like with the requirements on self-cleaning functions.

Description

technical field [0001] The invention belongs to the field of surface coatings, in particular to a self-healing super-amphiphobic and photocatalytic double self-cleaning coating and a preparation method thereof. Background technique [0002] Self-cleaning coating refers to a functional coating that can automatically degrade or fall off organic pollutants or dust on the surface of the substrate under the action of sunlight or rain. Self-cleaning coatings can be used in various textiles, such as outdoor clothing, medical protective clothing, shoes and hats, tents, etc. Coating self-cleaning coatings on the surface of solar panels can effectively solve the problem of reduced efficiency of solar equipment caused by the accumulation of dust. If the glass curtain wall of a high-rise building is coated with a self-cleaning coating, it can not only reduce cleaning costs, but also reduce the risk of cleaning workers working at heights. In recent years, self-cleaning coatings have re...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/08C09D127/18C09D5/16C08G77/24C08G77/06
CPCC08G77/06C08G77/24C08K2003/2241C09D5/1618C09D5/1637C09D5/1675C09D127/18C09D183/08C08L27/18C08K3/22C08L83/08
Inventor 赵燕王文建刘日平
Owner SUZHOU UNIV
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