Antibacterial material with adjustable antibacterial ability and preparation method thereof and application thereof
A technology of antibacterial materials and capabilities, applied in the field of antibacterial materials and their preparation, can solve the problems of inability to adjust antibacterial ability, long antibacterial time, poor antibacterial effect, etc., achieve stable effect, strong pertinence, and avoid the effect of external environment
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[0040] According to a preferred embodiment of the present invention, the chemical reduction method is to mix a chemical reducing agent with iron-containing natural clay,
[0041] The chemical reducing agent is a strong reducing agent, preferably selected from one or more of sodium dithionite, sodium hypophosphite, hydrazine hydrate or sodium bisulfite.
[0042] In a further preferred embodiment, the chemical reducing agent is one or more of sodium dithionite, sodium hypophosphite or sodium bisulfite.
[0043] In a further preferred embodiment, the chemical reducing agent is sodium dithionite.
[0044] According to a preferred embodiment of the present invention, the weight ratio of the iron-containing natural clay to the reducing agent is 1:(2-7), preferably 1:(3-6), more preferably 1:4.
[0045] According to a preferred embodiment of the present invention, the antibacterial regulator is a positive regulator that enhances the antibacterial ability of the reduced iron-containi...
Embodiment 1
[0126] (1) Take 1g of iron-containing nontronite (Sp_Clay_NAu-2; American Clay Society origin clay resource bank) and dissolve it in 100mL (sodium citrate-sodium bicarbonate buffer solution (the preparation method is to mix 1M sodium bicarbonate with 0.3M Sodium citrate is mixed according to the volume ratio of 8:1)), and ultrasonically stirred to make a suspension with a concentration of 10g / L, which is placed in a reaction container; the reaction container is first passed through nitrogen for 20min under the condition of a water bath at 100°C, and then Add 4g of sodium dithionite to it, continue to pass nitrogen gas for 5 minutes, seal the reactor, place it in an oven at 60°C for 24 hours, and obtain a reduced iron-containing nontronite. The reduced nontronite needs to be used in an anaerobic box. Wash three times with deionized water;
[0127] (2) Detect the concentration of ferrous iron in the reduced iron-containing nontronite, the steps are as follows:
[0128] (2.1) Ta...
Embodiment 2
[0134] The reduced iron-containing nontronite (calculated as ferrous iron), ascorbic acid and MES (pre-adjusted to pH 6) were mixed in a molar ratio of 3:2:2, and the three were shaken and mixed in an anaerobic operation box for 30 minutes. Freeze-drying is carried out under vacuum conditions to obtain antibacterial materials.
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