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A preparation method of an all-solid polymer electrolyte membrane containing biological materials

An all-solid polymer, electrolyte membrane technology, applied in fuel cells, circuits, electrical components, etc., can solve problems such as battery safety hazards

Active Publication Date: 2022-01-28
HARBIN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Lithium-ion batteries have received widespread attention and research because of their good safety, excellent energy density and very stable charge-discharge cycle performance. Electrolyte is one of the most important components of lithium-ion batteries. Its main function is To ensure the passage of lithium ions and prevent the passage of electrons, electrolytes can be divided into liquid electrolytes, gel electrolytes, and solid electrolytes according to their physical forms, but because liquid electrolytes and gel electrolytes contain liquid, the batteries made will have Potential safety hazards, in recent years people have begun to devote themselves to the development of safer solid-state electrolytes

Method used

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  • A preparation method of an all-solid polymer electrolyte membrane containing biological materials
  • A preparation method of an all-solid polymer electrolyte membrane containing biological materials
  • A preparation method of an all-solid polymer electrolyte membrane containing biological materials

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specific Embodiment approach 1

[0018] Embodiment 1: The preparation method of an all-solid polymer electrolyte membrane containing biological materials in this embodiment is carried out according to the following steps:

[0019] Step 1: Preparation of Starch Phthalate

[0020] Take starch, phthalic anhydride, pyridine and solvent, mix according to a certain ratio, blend and stir for 3~4 hours under the condition of 80 ℃ water bath, and then use isopropanol to precipitate starch phthalate ester, then in Dry it in a vacuum oven for 24 hours, and finally grind the starch phthalate into powder with a mortar for later use;

[0021] Step 2: Preparation of all-solid polymer electrolyte membrane

[0022] Weigh polyvinylidene fluoride, starch phthalate, lithium salt and solvent, blend and stir in a certain proportion to form a homogeneous solution, cast the stirred solution onto a glass plate, and then dry it in a vacuum oven for 1 hour. A polymer electrolyte membrane can be obtained.

specific Embodiment approach 2

[0023] Embodiment 2: The difference between this embodiment and Embodiment 1 is that the preparation method of an all-solid polymer electrolyte membrane containing biological materials described in Step 1 and Step 2 is characterized in that the solvent used It is N,N-dimethylformamide. Others are the same as in the first embodiment.

specific Embodiment approach 3

[0024] Embodiment 3: The difference between this embodiment and Embodiment 1 to 2 is that the method for preparing an all-solid polymer electrolyte membrane containing biological materials described in step 2 is characterized in that the lithium used The salt is lithium bistrifluoromethanesulfonimide. Others are the same as in the first or second embodiment.

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Abstract

The invention discloses a method for preparing an all-solid polymer electrolyte membrane containing biological materials, and relates to a method for preparing an electrolyte membrane for a lithium ion battery. Specifically, starch, phthalic anhydride, pyridine and solvent are mixed according to a certain ratio, blended and stirred in a water bath at 80°C for 3 to 4 hours, and then starch phthalate is precipitated with isopropanol. Then dry in a vacuum oven for 24 hours, and finally grind the starch phthalate into powder with a mortar for use. Then weigh the polyvinylidene fluoride, modified starch, lithium salt and solvent, blend and stir in a certain proportion to form a homogeneous solution, and then dry in a vacuum oven for 1 hour to obtain an all-solid polymer electrolyte membrane. The all-solid polymer electrolyte membrane prepared by the invention has good electrochemical performance, simple experimental process, wide application range and great application value.

Description

technical field [0001] The invention relates to a technology in the field of lithium ion batteries, in particular to a method for preparing an all-solid polymer electrolyte membrane containing biological materials. Background technique [0002] Lithium-ion batteries have received widespread attention and research because of their good safety, excellent energy density and very stable charge-discharge cycle performance. Electrolyte is one of the most important components of lithium-ion batteries. Its main function is To ensure the passage of lithium ions and prevent the passage of electrons, electrolytes can be divided into liquid electrolytes, gel electrolytes, and solid electrolytes according to their physical forms, but because liquid electrolytes and gel electrolytes contain liquid, the batteries made will have In recent years, people have begun to devote themselves to the development of safer solid-state electrolytes. [0003] Traditional polymer electrolytes are basical...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M8/1041H01M8/1069H01M8/1081
CPCH01M8/1041H01M8/1069H01M8/1081Y02E60/50
Inventor 李丽波谢明龙沧海
Owner HARBIN UNIV OF SCI & TECH