Low-cost energy storage luminescent paint and preparation method thereof

An energy-storage luminescent, low-cost technology, applied in luminescent coatings, anti-corrosion coatings, coatings, etc., can solve the problems of short afterglow time, high cost of energy storage coatings, and low brightness, so as to improve fluorescence life and reduce collision quenching Effect, the effect of prolonging the luminous time

Inactive Publication Date: 2019-07-30
CHONGQING JINHONG CONSTR ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the deficiencies of the above-mentioned prior art, the purpose of the present invention is to provide a low-cost energy storage luminous paint and its preparation method, which solves the problems of high cost, radioactivity, low brightness and short afterglow time of the existing energy storage paint

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] 1) Dissolve the rare earth aluminate long-lasting energy storage luminescent material in tetrahydrofuran, then add silica microspheres to obtain a mixed solution, and then place the mixed solution in an ultrasonic field with an ultrasonic power of 150W and an ultrasonic time of 1h. Make the rare earth aluminate long afterglow energy storage luminescent material into the silica microspheres, after the reaction is completed, add the silane coupling agent KH-550 and polyvinyl alcohol to fully react, wash and dry, to obtain modified microspheres;

[0031] 2) Add water, acrylic polymer copolymer emulsion, styrene-acrylic emulsion and dihydroxypropane to the modified microspheres prepared in step 1) and stir and disperse to obtain a mixed solution;

[0032] 3) Add non-ionic emulsifying wetting agent, propylene glycol butyl ether, mineral oil, hydrophobically modified copolymer ammonium salt dispersant, talcum powder, AMP-95 and SHP-50 to the mixed solution obtained in step 2) in se...

Embodiment 2

[0034] 1) Dissolve zinc sulfide powder in tetrahydrofuran, then add silica microspheres to obtain a mixed solution, and then place the mixed solution in an ultrasonic field with an ultrasonic power of 150W and an ultrasonic time of 1h to make the rare earth aluminate long afterglow The energy storage luminescent material enters the silica microspheres. After the reaction is completed, the silane coupling agent KH-550 is added to fully react with polyvinyl alcohol, washed, and dried to obtain modified microspheres;

[0035] 2) Add water, reactive self-crosslinking acrylate emulsion, styrene-acrylic emulsion and dihydroxypropane to the modified microspheres prepared in step 1) and stir and disperse for 15 minutes to obtain a mixed solution;

[0036] 3) Add non-ionic emulsifying wetting agent, propylene glycol butyl ether, mineral oil, hydrophobically modified copolymer ammonium salt dispersant, talcum powder, AMP-95 and SHP-50 to the mixed solution obtained in step 2) in sequence, sti...

Embodiment 3

[0038] 1) Dissolve the silicate self-luminous material in dimethylformamide, then add silica microspheres to obtain a mixed solution, and then place the mixed solution in an ultrasonic field with an ultrasonic power of 150W and an ultrasonic time of 1h, Make the rare earth aluminate long afterglow energy storage luminescent material into the silica microspheres, after the reaction is over, add the silane coupling agent KH-550 to fully react with polyvinyl alcohol, wash and dry, to obtain modified microspheres;

[0039] 2) To the modified microspheres prepared in step 1), add water, reactive acrylic acid ester multi-emulsion copolymer emulsion, styrene-acrylic emulsion and dihydroxypropane and stir and disperse for 15 minutes to obtain a mixed solution;

[0040] 3) Add non-ionic emulsifying wetting agent, propylene glycol butyl ether, modified paraffin, hydrophobically modified copolymer ammonium salt dispersant, talcum powder, AMP-95 and FN80 to the mixed solution obtained in step 2...

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Abstract

The invention discloses a low-cost energy storage luminescent paint and a preparation method thereof. The low-cost energy storage luminescent paint is prepared from, by weight, 30-50 parts of silicondioxide microspheres, 2-3 parts of a coupling agent, 20-30 parts of luminous powder, 10-25 parts of polyvinyl alcohol, 15-25 parts of an acrylic acid emulsion, 10-20 parts of a styrene-acrylic emulsion, 0.5-1 part of a wetting agent, 1-5 parts of dihydroxypropane, 0.1-0.2 part of an antifoaming agent, 0.05-2 parts of a dispersing agent, 0.2-0.5 part of talcum powder, 0.1-0.5 part of a water repellent, 0.1-0.5 part of a coalescing agent, 0.1-0.5 part of a thickening agent, 0.1-0.5 part of a pH adjuster and 10-15 parts of water. The low-cost energy storage luminescent paint and the preparation method thereof have the advantages that fluorescent powder is embedded in the silicon dioxide microspheres, and the surfaces of the silicon dioxide microspheres are modified with the polyvinyl alcohol,so that not only is the luminous efficiency of the fluorescent powder improved, but also the stability of the fluorescent powder is improved, the service life and lighting time of the paint are prolonged, the environmental friendliness is achieved, the brightness of the coating is high, the persistence time is long, the adhesion and corrosion resistance are good, and the application prospects aregood.

Description

Technical field [0001] The present invention relates to the field of luminous paint, in particular to a low-cost energy storage luminous paint and a preparation method thereof. Background technique [0002] Traditional road traffic markings are highly recognizable during the day, which can meet the requirements of traffic safety. However, at night, especially in an environment with insufficient lighting conditions, the degree of recognition is greatly reduced, and even the function of controlling and guiding traffic is lost, which seriously threatens road traffic safety. In public places, when the power is cut off in an emergency, the dark environment is likely to cause safety hazards. [0003] Energy storage coatings work in the form of "light absorption-light storage-self-luminescence". By absorbing and storing the light energy of daytime natural light, motor vehicles and various lighting lights, it is used as a luminous source at night and without light, without any other Ener...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/04C09D125/14C09D5/22C09D5/08
CPCC09D5/08C09D5/22C09D133/04C08L25/14C08K13/06C08K9/06C08K9/08C08K7/26C08K3/24C08K3/34
Inventor 刘雪梅周晓鸿翁铃林
Owner CHONGQING JINHONG CONSTR ENG
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