Macrocyclic nano cross-linking membrane based on Reso hydrocarbon and preparation method and application thereof
A technology of lassocarbon and cross-linked membrane, which is applied in the field of preparation of nano-cross-linked membrane to achieve the effect of good selective separation
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[0031] A preparation method and characterization application of a macrocyclic nano-crosslinked film based on ratholane, using C-methylcalix[4]resorcinol (commonly known as ratholane, MC4RA), terephthaloyl chloride (TC) With hypericin (HPC) as raw materials, macrocyclic nano-crosslinked binary membrane pTC-MC4RA and ternary membrane pTC-HPC-MC4RA were prepared on the surface of commercial aqueous membrane or organic membrane by interfacial crosslinking method. The chemical structural formula is as follows:
[0032]
[0033] The structural formula of the obtained nano-crosslinked binary membrane pTC-MC4RA is:
[0034]
[0035] The structural formula of the obtained nano-crosslinked ternary membrane pTC-HPC-MC4RA is:
[0036]
[0037] The preparation method and characterization application of the macrocyclic nano-crosslinked membrane based on ratholane of the present invention are described in detail below through four aspects:
[0038] 1. Preparation of binary nano-cr...
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