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Macrocyclic nano cross-linking membrane based on Reso hydrocarbon and preparation method and application thereof

A technology of lassocarbon and cross-linked membrane, which is applied in the field of preparation of nano-cross-linked membrane to achieve the effect of good selective separation

Inactive Publication Date: 2019-11-05
NANKAI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is still a huge challenge to simultaneously improve the permeability and selectivity in the membrane separation process and to balance the relationship between the two.

Method used

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  • Macrocyclic nano cross-linking membrane based on Reso hydrocarbon and preparation method and application thereof
  • Macrocyclic nano cross-linking membrane based on Reso hydrocarbon and preparation method and application thereof
  • Macrocyclic nano cross-linking membrane based on Reso hydrocarbon and preparation method and application thereof

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Experimental program
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Embodiment

[0031] A preparation method and characterization application of a macrocyclic nano-crosslinked film based on ratholane, using C-methylcalix[4]resorcinol (commonly known as ratholane, MC4RA), terephthaloyl chloride (TC) With hypericin (HPC) as raw materials, macrocyclic nano-crosslinked binary membrane pTC-MC4RA and ternary membrane pTC-HPC-MC4RA were prepared on the surface of commercial aqueous membrane or organic membrane by interfacial crosslinking method. The chemical structural formula is as follows:

[0032]

[0033] The structural formula of the obtained nano-crosslinked binary membrane pTC-MC4RA is:

[0034]

[0035] The structural formula of the obtained nano-crosslinked ternary membrane pTC-HPC-MC4RA is:

[0036]

[0037] The preparation method and characterization application of the macrocyclic nano-crosslinked membrane based on ratholane of the present invention are described in detail below through four aspects:

[0038] 1. Preparation of binary nano-cr...

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Abstract

The invention provides a macrocyclic nano cross-linking membrane based on Reso hydrocarbon and a preparation method and application thereof. The preparation method of the macrocyclic nano cross-linking membrane based on the Reso hydrocarbon comprises the steps that MC4RA and TC are used as a raw material, a macrocyclic nano cross-linking membrane pTC-MC4RA is prepared on the surface of a commercial drainage membrane or an organic membrane by adopting an interface cross-linking method, then, the pTC-MC4RA membrane is used as a basic framework, a small amount of HPC capable of generating singletoxygen is doped in an aqueous solution of the Reso hydrocarbon, through an interface cross-linking reaction among MC4RA, HPC and TC, a pTC-HPC-MC4RA membrane which is basically constant with a pTC-MC4RA structure is prepared, a germ experiment shows that the three-component cross-linking membrane can filter germs, can further kill the germs in situ in the light, and important significance is achieved for thoroughly removing the germs in drinking water. The preparation method of the macrocyclic nano cross-linking membrane based on the Reso hydrocarbon has the advantages that the preparation method is simple and easy to implement, use level costs of the Reso hydrocarbon and hypericin are low, and thus wide application prospects are achieved in the membrane filtering fields.

Description

technical field [0001] The invention relates to the preparation technology of nano cross-linked membranes, in particular to the preparation and characterization of nano cross-linked membranes based on macrocyclic host ratholane and its application in filtering dyes and sterilizing bacteria. Background technique [0002] Water treatment is closely related to our life. For example, dyes in industrial wastewater will cause great pollution to the environment, and bacteria in drinking water will cause harm to the human body. Therefore, for environmental protection and human health, it is necessary to remove dyes and Bacteria in drinking water is particularly important. Traditional energy-intensive separation technologies often bring heavy burdens to the economy and the environment during industrial production, while high-performance membrane separation technology has the advantages of simple process, low energy consumption, and no secondary pollution, and has become a kind of Ve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D67/00B01D69/12B01D71/76C02F1/44C08J9/40C08J3/24C08L77/02C08L81/06C02F101/30
CPCB01D69/125B01D71/76B01D2325/18C02F1/44C02F2101/308C02F2303/04C08J3/24C08J9/405C08J2377/02C08J2381/06
Inventor 刘育刘江华张瀛溟
Owner NANKAI UNIV
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