Toughened PA/ABS alloy material and preparation method thereof

A kind of alloy material, strengthening and toughening technology, applied in the field of strengthening and toughening PA/ABS alloy material and its preparation, can solve the problems of poor compatibility, difficulty in strengthening and toughening, and reduced tensile strength, etc., to achieve bending strength toughening, Resistant to hydrolysis, the effect of reducing the amount of addition

Active Publication Date: 2019-12-20
铨盛(云浮)新型聚合物有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the compatibility between nylon and ABS is poor, and it is often necessary to add a compatibilizer to it to improve the toughness of the PA / ABS alloy material; and due to the existence of butadiene segments in ABS, it is bound to cause PA / ABS alloy The tensile strength of the material is reduced, but the existing compatibilizers cannot solve this problem, so how to achieve toughness is a major difficulty in the preparation of PA / ABS alloy materials

Method used

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  • Toughened PA/ABS alloy material and preparation method thereof
  • Toughened PA/ABS alloy material and preparation method thereof
  • Toughened PA/ABS alloy material and preparation method thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0039] A toughened PA / ABS alloy material, comprising the following raw materials in parts by weight:

[0040]

[0041] The compatibilizer is an epoxy-type compatibilizer with a long side chain structure.

[0042] The polyamide is PA6.

[0043] The rubber content of the ABS high rubber powder is 60 wt%, and the acrylonitrile content of the ABS high rubber powder is 28 wt%.

[0044] Such as figure 1 Shown, the preparation method of described compatibilizer comprises the steps:

[0045] (A1), 20 parts of aromatic vinyl monomers, 6 parts of long alkyl methacrylate monomers and 6 parts of epoxy unsaturated hydrocarbons were uniformly mixed by weight to obtain mixed monomers;

[0046] (A2), add 35 parts of dispersant-water solution to the mixed monomer obtained in step (A1), then add 0.2 parts of initiator under continuous stirring conditions, heat up to 78 ° C for 7 hours, then centrifuge, wash and dry, Get compatibilizer.

[0047] The aromatic vinyl monomer is styrene; the...

Embodiment 2

[0057] A toughened PA / ABS alloy material, comprising the following raw materials in parts by weight:

[0058]

[0059] The compatibilizer is an epoxy-type compatibilizer with a long side chain structure.

[0060] The polyamide is prepared by mixing PA66 and PA11 in a weight ratio of 1:1.

[0061] The rubber content of the ABS high rubber powder is 50 wt%, and the acrylonitrile content of the ABS high rubber powder is 20 wt%.

[0062] The preparation method of described compatibilizer comprises the steps:

[0063] (A1), by weight, 10 parts of aromatic vinyl monomers, 2 parts of long alkyl methacrylate monomers and 2 parts of epoxy unsaturated hydrocarbons are uniformly mixed to obtain mixed monomers;

[0064] (A2), add 30 parts of dispersant-water solution to the mixed monomer obtained in step (A1), then add 0.1 part of initiator under continuous stirring conditions, raise the temperature to 70 ° C for 6 hours, then centrifuge, wash and dry, Get compatibilizer.

[0065] ...

Embodiment 3

[0075] A toughened PA / ABS alloy material, comprising the following raw materials in parts by weight:

[0076]

[0077] The compatibilizer is an epoxy-type compatibilizer with a long side chain structure.

[0078] The polyamide is prepared by mixing PA46 and PA7 at a weight ratio of 1:1.

[0079] The rubber content of the ABS high rubber powder is 70 wt%, and the acrylonitrile content of the ABS high rubber powder is 35 wt%.

[0080] The preparation method of described compatibilizer comprises the steps:

[0081] (A1), uniformly mix 30 parts of aromatic vinyl monomers, 10 parts of long alkyl methacrylate monomers and 10 parts of epoxy unsaturated hydrocarbons in parts by weight to obtain mixed monomers;

[0082] (A2), add 40 parts of dispersant-water solution to the mixed monomer obtained in step (A1), then add 0.3 parts of initiator under continuous stirring conditions, heat up to 85 ° C for 8 hours, then centrifuge, wash and dry, Get compatibilizer.

[0083] The aromatic...

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Abstract

The invention relates to the technical field of polymer alloy materials, in particular to a toughened PA/ABS alloy material and a preparation method thereof. The toughened PA/ABS alloy material comprises the following raw materials: polyamide, ABS high rubber powder, a compatilizer and an antioxidant, wherein the compatilizer is an epoxy type compatilizer with a long side chain structure. The toughened PA/ABS alloy material can enhance the tensile strength, bending strength and toughness at the same time, and realizes toughening.

Description

technical field [0001] The invention relates to the technical field of polymer alloy materials, in particular to a toughened PA / ABS alloy material and a preparation method thereof. Background technique [0002] PA (also known as nylon, polyamide) and ABS are two important plastic products, among which nylon has excellent mechanical properties, heat resistance, wear resistance, chemical resistance and self-lubrication, and low friction coefficient. It has a certain flame retardancy and is easy to process. It is suitable for filling with glass fiber and other fillers to improve performance and expand the scope of application. ABS is a thermoplastic polymer material with high strength, good toughness and easy processing. , according to the different proportions of the three monomers, it can be applied to various plastic products, and its main advantage is low price. By making two kinds of plastics into alloys, new products with excellent performance can be obtained. [0003] H...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L77/06C08L55/02C08L25/14C08L25/16C08K5/134C08K5/13C08F212/08C08F220/32C08F220/18C08F212/12
CPCC08L77/02C08L77/06C08F212/08C08F212/12C08L2201/08C08L2205/08C08L2205/03C08L2205/035C08L55/02C08L25/14C08K5/1345C08L25/16C08K5/13
Inventor 王启瑶任雪峰孙佳男覃韦崴
Owner 铨盛(云浮)新型聚合物有限公司
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