Curable liquid composition, composition-accommodating container, liquid composition discharging device, cured material, and method of manufacturing cured material
A technology of liquid composition and discharge device, applied in the directions of inking device, application, coating, etc., can solve problems such as inappropriateness
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[0238] Hereinafter, examples are shown, and the present invention will be described in more detail, but the present invention is not limited by these examples.
[0239] Evaluation method of SI value
[0240] The above-mentioned SI value was subjected to a skin allergy test using the LLNA method (Local Lymph Node Assay), and was determined as follows.
[0241] experiment material
[0242] positive control substance
[0243] As the positive control substance, α-hexylcinnamaldehyde (HCA, manufactured by Wako Pure Chemical Industries, Ltd.) was used.
[0244] medium
[0245] As the above medium, use the following mixture:
[0246] Acetone (manufactured by Wako Pure Chemical Industries, Ltd.) 4 parts by volume
[0247] Olive oil (manufactured by Fujimi Pharmaceutical) 1 part by volume
[0248] experimental animals
[0249] With regard to the tested substances, positive control, vehicle control, female mice were acclimatized for 8 days, which included 6 days of quarantine. D...
Embodiment 1~9 and comparative example 1~4
[0296] The following materials A to C were mixed according to the compounding ratios (values are parts by mass) shown in the columns of Examples and Comparative Examples in Table 3 to prepare inks.
[0297] A: Monomers whose SI value is less than 3.0, of course, those who are negative for skin sensitization determined by other methods and equipment are included here.
[0298] B: A photopolymerization initiator having a molecular weight of less than 500.
[0299] C: A photopolymerization initiator having a molecular weight of 500 or more.
[0300] Details of A1 to A8, B1 to B3, and C1 to C6 described in Table 3 are as follows. The values in parentheses at the end are the SI values in the LLNA test, and "none" means those evaluated as "negative for skin sensitization" or "no skin sensitization" in SDS (Safety Data Sheet). "There is no Globally Harmonized System (GHS) icon for the classification and labeling of chemicals that indicate hazards and hazards in the SDS" means...
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