a cote 2 /mxene composite material and preparation method thereof

A technology of composite materials and preparation steps, which is applied in the direction of structural parts, electrical components, battery electrodes, etc., can solve the problems of inability to obtain rapid ion migration effect, electrode material crushing, and fast capacity decay, and achieve large transfer and ion adsorption area and Vacuum, prevention of agglomeration, and high production efficiency

Active Publication Date: 2022-04-08
WUYI UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, transition metal compounds tend to exhibit huge volume expansion during the charge-discharge cycle, causing the electrode material to be pulverized, resulting in poor rate performance and fast capacity fading during the cycle process.
Therefore, how to solve the problems of poor rate performance and fast capacity fading during the cycling process of transition metal compounds has become a major technical obstacle in this field.
[0006] As a new type of transition metal carbon or nitride, MXene has the advantages of excellent electrical conductivity and mechanical properties, high hydrophilic surface and ion transport performance due to its unique layered structure and rich and adjustable components. It is hoped to overcome the problems of poor rate performance and fast capacity fading during the cycle of transition metal compounds, but the interlayer distance is small, and the surface functional groups have certain adsorption properties, so it cannot achieve the ideal fast ion migration effect when used alone.

Method used

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  • a cote  <sub>2</sub> /mxene composite material and preparation method thereof
  • a cote  <sub>2</sub> /mxene composite material and preparation method thereof
  • a cote  <sub>2</sub> /mxene composite material and preparation method thereof

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preparation example Construction

[0044] The invention provides a CoTe 2 The preparation method of / MXene composite material, wherein, CoTe 2 For the synthesis method, please refer to:

[0045] "Xiao Peipei, Zhu Yongchun, Qian Yitai. Synthesis of patterned CoTe_2 ultrafine nanorod bundles by Te nanorod in situ template method with the assistance of CTAB[C].";

[0046] "China Instrument Functional Materials Society, Jiangsu University, "Functional Materials" journal, "Functional Materials Information" journal. Proceedings of the 2009 China Functional Materials Technology and Industry Forum.";

[0047] "Chinese Society of Instrument Functional Materials, Jiangsu University, "Functional Materials" Journal, "Functional Materials Information" Journal: Instrument Materials Branch of China Instrumentation Society, 2009:799-800.".

Embodiment 1

[0049] A CoTe 2 The preparation method of / MXene composite material, comprises the following steps:

[0050] (1) Take 0.1mmol MXene (Ti 3 C 2 T x ) was added to N, N-dimethylformamide, configured into a 1 mg / ml dispersion, and stirred magnetically for 2 hours;

[0051] (2) Add 0.1mmol Co(NO 3 ) 2 ·6H 2 O and 0.1mmol urea were added in the dispersion liquid described in step (1), and stirred for 3 hours;

[0052] (3) Transfer the dispersion liquid obtained in step (2) into a reaction kettle with a capacity of 50ml, seal it, place it in an oven, heat it to 80°C, keep it warm for 8h, and then cool it to room temperature;

[0053] (4) Centrifuge the product obtained in step (3) for 5 minutes under the condition of 5000r / min, and wash the filter residue 3 times alternately with deionized water and absolute ethanol;

[0054] (5) Dry the centrifuged product obtained in step (4) in a vacuum drying oven at a drying temperature of 60°C and a drying time of 6 hours to obtain the p...

Embodiment 2

[0062] A CoTe 2 The preparation method of / MXene composite material, comprises the following steps:

[0063] (1) Take 0.2mmol MXene (Ti 3 C 2 T x ) was added to N, N-dimethylformamide, configured into a 5 mg / ml dispersion, and magnetically stirred for 4 hours;

[0064] (2) 0.2mmol Co(NO 3 ) 2 ·6H 2 O and 0.25mmol urea were added in the dispersion liquid described in step (1), and stirred for 9 hours;

[0065] (3) Transfer the dispersion liquid obtained in step (2) into a reactor with a capacity of 50ml, seal it, place it in an oven, heat it to 150°C, keep it warm for 15h, and then cool it to room temperature;

[0066] (4) Centrifuge the product obtained in step (3) for 8 minutes under the condition of 6000r / min, and wash the filter residue 3 times alternately with deionized water and absolute ethanol;

[0067] (5) Dry the centrifuged product obtained in step (4) in a vacuum drying oven at a drying temperature of 60°C and a drying time of 10 hours to obtain the precursor...

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Abstract

The invention discloses a CoTe 2 The preparation method of the / MXene composite material comprises the following steps: adding the MXene material to the dispersant to prepare a dispersion liquid with a concentration of 1-10mg / ml; adding the cobalt source and the reducing agent to the above dispersion liquid, stirring and dissolving, and obtaining a mixed liquid; the above mixed solution is heated, cooled, centrifuged, washed and dried to obtain the precursor Co(OH) 2 / MXene; the above precursor Co(OH) 2 / MXene and tellurium source are heated according to the molar ratio of 1:1~6, cooled to obtain the crude product; the above crude product is centrifuged at 5000-8000r / min for 5-10min, washed and dried to obtain CoTe 2 / MXene composites. CoTe prepared by the present invention 2 The / MXene composite material is applied to the negative electrode of potassium ion batteries. It has good cycle stability, high specific capacity and excellent rate performance, and has the advantages of low cost, abundant resources, and simple preparation methods. It is suitable for large-scale production of potassium ion batteries. with application.

Description

technical field [0001] The invention belongs to the technical field of new energy, and in particular relates to a CoTe 2 / MXene composite material and its preparation method. Background technique [0002] Since the 21st century, with the increasing demand for energy in modern society, fossil energy has been continuously consumed and depleted, and environmental problems have become increasingly serious, seriously affecting the sustainable development of human society. Therefore, the research and development of new renewable clean energy has been become the focus of current research. [0003] At present, as a secondary battery energy storage system, lithium-ion batteries have achieved great success in the fields of electric vehicles and portable electronic devices. The uneven distribution has led to rising prices of lithium-ion batteries, which limits their application in the field of energy storage. Therefore, developing a new type of secondary alkali metal battery has ext...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/36H01M4/58H01M4/136H01M10/054B82Y40/00
CPCH01M4/362H01M4/58H01M4/581H01M4/136H01M10/054B82Y40/00Y02E60/10
Inventor 张业龙徐晓丹周健文孙宏阳陈浩彭章泉
Owner WUYI UNIV
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