Flexible transparent ionic gel electrode and preparation method thereof

A kind of ion gel, transparent technology, applied in the field of flexible transparent ion gel electrode and its preparation, can solve the problems such as the adverse effect of the conductivity of the hydrogel material, the adverse effect of the hydrogel material, the binding and binding of the hydrogel, etc.

Active Publication Date: 2021-09-14
BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, since elastomers tend to be electrically insulating, the modification of surface elastomers may adversely affect the application of hydrogel materials in flexible electronics.
In addition, the elastomer material only physically blocks the evaporation of water in the hydrogel, and cannot combine and bind the water molecules in the hydrogel through forces such as hydrogen bonds, nor can it improve the anti-icing performance of the hydrogel.
Moreover, hydrogels and elastomers are two types of polymer materials with large differences in properties. Although the interfacial layers between them can be combined through polymerization, the two-phase interface still delaminates and falls off during long-term use.
For most organic hydrogels, the presence of organic solvents may adversely affect the conductivity of the hydrogel material, increase the material resistance, and the toxicity of organic solvents needs to be considered
[0007] Therefore, it is urgent to develop a new type of flexible transparent electrode, which can solve the problems of long-term storage and low temperature resistance.

Method used

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  • Flexible transparent ionic gel electrode and preparation method thereof
  • Flexible transparent ionic gel electrode and preparation method thereof
  • Flexible transparent ionic gel electrode and preparation method thereof

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preparation example Construction

[0033] The invention provides a method for preparing a flexible transparent ion gel electrode, comprising: S1) polymerizing an acrylamide monomer and / or a first acrylic monomer in the presence of a crosslinking agent to obtain a network structure polymer; S2) fully immerse the above-mentioned network structure polymer in the solution containing the second acrylic acid monomer to fully swell, and then heat to carry out polymerization reaction to obtain a double network structure polymer; S3) above-mentioned double network structure polymer Fully swollen in the ionic solution, a flexible transparent ion gel electrode is obtained.

[0034] Among them, the present invention has no special limitation on the sources of all raw materials, which can be commercially available. In the present invention, unless otherwise specified, the acrylic monomers refer to acrylic monomers and derivative monomers thereof, including ester-formed monomers.

[0035]Polymerize the first acrylamide mono...

Embodiment 1

[0046] 1.1 Configuration of polymer network pre-polymerization liquid and ionic solution:

[0047] Based on the copolymer of acrylic acid (AA) and [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfonic acid propyl)ammonium hydroxide (TB), the crosslinking agent used For methylene bisacrylamide (BIS), the molecular formulas of the two monomers and the crosslinking agent are as follows figure 1 shown.

[0048] (1) The molar ratio of the two monomers in the configured first polymer prepolymerization liquid is AA / TB=0:1. Take the 300mL aqueous solution system as an example for the pre-polymerization liquid, weigh 176.7g of TB, 0.3g of BIS crosslinking agent and 0.9g of ammonium persulfate initiator, dissolve them in 300ml of water, stir at room temperature to fully dissolve, pass nitrogen to remove oxygen, and place in 4 Store in ℃ environment.

[0049] (2) The molar ratio of the two monomers in the prepared second polymer prepolymerization solution is AA / TB=4:1. Take the 275mL aqueou...

Embodiment 2

[0061] 2.1 The first polymer network pre-polymerization liquid solution (the pre-polymerization liquid prepared by taking 300mL aqueous solution system as an example, weighed 80.4 grams of N,N-diethylacrylamide (DEA), 0.3 grams of BIS crosslinking agent and 0.9 grams Ammonium persulfate initiator, dissolved in 300 ml of water, stirred at room temperature to fully dissolve, nitrogen gas to remove oxygen) and poured into the mold after uniform stirring, in the accelerator N,N,N',N'-tetramethylethylenediamine (225μL ) in the presence of free radical polymerization at 4 ° C to synthesize a transparent gel, and finally remove impurities to obtain the first network structure polymer.

[0062] 2.2 Use the second polymer network pre-polymerization solution for the prepared first polymer network (the molar ratio of the two monomers in the configured pre-polymerization solution is AA / TB=8:2. The pre-polymerization solution is 275mL aqueous solution system as an example, Take by weighing...

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Abstract

The invention provides a preparation method of a flexible transparent ionic gel electrode, which comprises the following steps: S1) carrying out polymerization reaction on a first acrylamide monomer and/or a first acrylic monomer in the presence of a cross-linking agent to obtain a polymer with a network structure; S2) fully soaking the polymer with the network structure in a solution containing a second acrylic monomer and/or a second acrylamide monomer for fully swelling, and then conducting heating for polymerization reaction to obtain a polymer with a dual-network structure; and S3) fully swelling the polymer with the double-network structure in an ionic solution to obtain the flexible transparent ionic gel electrode. Compared with the prior art, the preparation method is simple, and the prepared electrode has the characteristics of transparency, softness, high mechanical property and high conductivity, still has relatively high conductivity at low temperature, and can be applied to the field of electronic equipment such as flexible sensors and wearable equipment in an extreme environment.

Description

technical field [0001] The invention belongs to the technical field of flexible electrodes, in particular to a flexible transparent ion gel electrode and a preparation method thereof. Background technique [0002] With the continuous advancement of electronic technology, flexible electronic technology has been developed and developed rapidly in order to meet people's ever-increasing life and health needs, which will lead to a new intelligent revolution in the future. Flexible electrodes are the core components of flexible electronic devices, especially the flexible transparent electrodes developed in recent years play a decisive role in touch screen display, skin wearable and implantable electronic devices. [0003] Flexible transparent electrodes are generally printed on elastomer substrates, and folding, twisting, stretching, etc. are common deformation modes. In recent years, with the development of nanomaterials and polymer materials, a variety of materials that can be ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J3/03C08F220/38C08F220/06C08F220/54C08L33/02C08L33/14C08L33/24
CPCC08J3/03C08F220/06C08F220/387C08F220/54C08J2333/02C08J2433/14C08J2433/24C08F222/385
Inventor 高海南毛佳乐师琪陈哲之穆凯代斯·阿布来孜
Owner BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
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