Triarylamine organic compound containing pyrene structure and application thereof
An organic compound, triarylamine technology, applied in the field of triarylamine organic compounds, can solve different problems and achieve the effect of improving device efficiency
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[0045]Embodiment 1: the synthesis of target compound
[0046]
[0047] Under nitrogen atmosphere, add 0.06mol raw material B in the three-neck flask of 500ml, add mixed solvent (300ml toluene, 90ml H 2 O) it is dissolved, and nitrogen gas is stirred for 1 hour, then slowly add 0.05mol raw material A, 0.1mol K 2 CO 3 , 0.005mol Pd(PPh 3 ) 4 , heated to 90° C., reacted for 8 hours, and observed the reaction by thin layer chromatography (TLC) until the reaction was complete. After naturally cooling to room temperature, water was added to the reaction system for extraction, liquid separation, and the organic phase was rotary evaporated under reduced pressure until there was no distillate. The resulting material was purified by silica gel column to afford intermediate N.
[0048] Under a nitrogen atmosphere, add 0.06mol intermediate N to a 500ml three-necked flask, add a mixed solvent (300ml toluene, 90ml H 2 O) dissolve it, and stir for 1 hour with nitrogen gas, then slow...
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