Catalytic cracking catalyst and its prepn

A catalyst and binder technology, which is applied in the field of catalytic cracking catalysts, can solve the problems that the pore structure of the catalyst matrix cannot be improved, the coke selectivity of the cracking reaction is poor, the corrosion equipment and the modification process are complicated, and the performance of the pore structure can be improved. , Enhanced heavy oil conversion capacity and large processing capacity

Inactive Publication Date: 2003-08-20
PETROCHINA CO LTD
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  • Abstract
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Problems solved by technology

[0005] Although the above-mentioned patents use acid-base modified clay as a matrix component to improve properties such as matrix pore structure, it has many advantages, but there are problems of corrosion equipment and complicated modification process; acid-soluble alumina has better bonding properties and It has a certain activity, but there is a problem of acid corrosion to the equipment. At the same time, the acid treatm

Method used

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  • Catalytic cracking catalyst and its prepn
  • Catalytic cracking catalyst and its prepn

Examples

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Embodiment 1~8

[0031] Fully mix quantitative medium and macroporous alumina, zeolite, binder, clay, and deionized water, stir for 2 hours, homogenize, and spray dry to shape. The resulting microspheres were calcined at 450°C for 0.5 hours. Get 1 kilogram of calcined microspheres, add 10 kilograms of deionized water and 0.225 kilograms of ammonium chloride, stir and wash at 75 ℃ for 20 minutes, add ammonium phosphate after filtering (making the catalyst phosphorus content be 1.0 weight %) and 10 kilograms of deionized water , stirred and washed at 75°C for 10 minutes, filtered and dried to obtain the catalysts of Examples 1-8 of the present invention. Table 1 shows the compositions and dosages of the catalysts in Examples 1 to 8.

[0032] Table 1 Embodiment 1~8 Catalyst each composition and consumption Comparative example 1-4

[0033] Compared with Examples 1-8, only pseudo-boehmite and boehmite are not used in the preparation of the catalyst, and the amount of kaolin is incre...

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Abstract

The catalytic cracking catalyst contains medium and large pore alumina with average pore size not smaller than 3 nm 5-60 wt%, zeolite 5-60 wt%, adhesive 5-40 wt% and clay 5-85 wt%. The preparation process includes mixing the said materials, spraying, roasting, washing and drying. Compared with conventional catalyst, the catalyst has strengthened heavy oil converting capacity, obviously improved gasoline and coke selectivity and strengthened heavy metal nickel resistance.

Description

technical field [0001] The invention relates to a catalytic cracking catalyst, in particular to a catalytic cracking catalyst containing medium and macroporous alumina. Background technique [0002] For the petroleum refining industry, high bottom oil conversion, high gasoline and low coke selectivity are always the goals pursued by catalytic cracking unit production. By improving the properties of zeolite and matrix, the catalytic cracking catalyst is adapted to the requirements of the above objectives. For quite a long time in the past, the improvement of zeolite has always been dominant. In recent years, with the increasingly heavy feed oil (high boiling point components >500 °C increase), inferior quality and the development of catalytic cracking process, the matrix The role is becoming more and more prominent, requiring the matrix of the catalyst to have medium and large pores and a certain activity, thereby improving the ability to crack heavy oil; at the same time...

Claims

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Application Information

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IPC IPC(8): C10G11/02
Inventor 庞新梅孙书红赵连鸿丁伟高雄厚
Owner PETROCHINA CO LTD
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