Space length adjustable crystal gel and method for preparing same
A technology of spacing and crystal gel, applied in the field of adjustable spacing crystal gel and its preparation, can solve the problems of non-closely packed colloidal crystal gel research that has not been reported, and achieve regular crystal gel arrangement, uniform properties, and better crystal gel arrangement. Effect
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Embodiment 1
[0020] A crystal glue with adjustable spacing, the spectral energy gap of the prepared crystal glue with adjustable spacing is from 200nm to 900nm.
Embodiment 2
[0022] A preparation method for preparing crystal glue with adjustable spacing, which is carried out in the following steps:
[0023] 1) Dialyze the colloidal spherical particles with a diameter of 80-250nm in water with a voltage of 500-3000V, and replace the dialysis water after each dialysis for at least 10 minutes until the conductivity of the dialysis water is 0.1-10μs / cm. The colloid was subjected to ultrasonic treatment for more than 1 minute,
[0024] 2) Dilute the colloid after ultrasonic dispersion to a volume concentration of 3-20% with a monomer solution of a neutral hydrogel polymer, and add an initiator caused by ultraviolet light to the diluted colloid solution and mix well, the The volume-to-weight ratio of the colloid solution and the initiator initiated by ultraviolet light is 100: (1~0.1), and the monomer solution of the above-mentioned neutral hydrogel polymer includes acrylamide polymer monomer and formazan as crosslinking agent Acrylamide, the molar rati...
Embodiment 3
[0026] A kind of preparation method that is used for preparing the crystal gel with adjustable spacing that the wavelength is 300nm, carries out according to the following steps successively:
[0027] 1) Dialyze the colloidal spherical particles with a diameter of 80nm in water with a voltage of 500-3000V, and replace the dialysis water after each dialysis for at least 10 minutes until the conductivity of the dialysis water is 0.1-10μs / cm,
[0028] 2) Ultrasonic treatment of the colloid after electric field dialysis for more than 1 minute,
[0029] 3) The colloid after ultrasonic dispersion is diluted to a volume concentration of 16.0% with a monomer solution of a neutral hydrogel polymer, and an initiator caused by ultraviolet light is added to the diluted colloid solution and mixed evenly, the colloid solution The volume-to-weight ratio of the initiator initiated by ultraviolet light is 100: (1-0.1), and the monomer solution of the above-mentioned neutral hydrogel polymer in...
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