Inner magnetic shield material for cathode ray tube and process for producing the same
A magnetic shielding material and magnetic shielding technology, applied in cathode ray tube/electron beam tube, inorganic material magnetism, metal material coating process, etc., can solve the problems of shortened service life of CRT, easy to fall off, and electron gun rupture.
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Embodiment 1
[0112] A 0.15 mm thick cold-rolled steel bar manufactured by hot-rolling and cold-rolling a low-carbon, aluminum-deoxidized steel having the composition shown in Table 1 (remainder: Fe and unavoidable impurities) was used as a base material. The cold-rolled steel bar passes through the 800°C N in the continuous annealing device 2 Annealed by heat treatment in atmosphere for 5 seconds, and then leveled. In this example, the rolls used in the skin pass and the rolling conditions were changed in order to adjust the surface roughness of the steel bar.
[0113] the element
C
Si
mn
P
S
quality%
0.002
0.01
0.25
0.009
0.003
[0114] In this example, the internal magnetic shielding material was prepared as follows: Cold-rolled steel strips with a surface roughness (Ra) of 0.5 μm were pretreated on a continuous production line using the method shown in Table 2, and then coated by roll coating. The resin coating comp...
Embodiment 2
[0137] On the pretreated cold-rolled steel strip, a urethane-based organic resin coating film was formed in the same manner as described in Example 1. The cold-rolled steel strip, the pretreatment method and the thickness of the resin coating film used are all the same as in Example 1. The results of coating properties and reddishness examined in the same manner as in Example 1 are shown in Table 3.
[0138] In the present embodiment, the pretreatment was carried out by the method shown in Table 3, and formed the following four different types of organic resin coating films:
[0139] - films (indicated by A) consisting only of organic resin A;
[0140] - a film containing coupler B in the resin (indicated by A+B);
[0141] - films containing metal oxide C in resin (denoted by A+C); and
[0142] - A film containing both the coupling agent B and the metal oxide C in the resin (indicated by A+B+C).
[0143] Organic resin A is the resin of the same commercially available water...
Embodiment 3
[0148] Except that waxes with different average particle diameters were further added to the coating film in different amounts, the organic resin coating film was tested under the same conditions as the organic resin coating film A+B+C in Experiment No. 1 of Tables 1 and 2. form.
[0149] Therefore, the cold-rolled steel bar with a surface roughness of 0.5 μm is pretreated sequentially by alkali deoiling→hot water washing→application solution (1) (sulfuric acid solution)→hot water washing. Therefore, on the same production line, a steel bar was coated with the resin coating composition on a roll, and baked in the same manner as in Example 1 to form resin coating films with different thicknesses. The coating composition used was the same commercially available urethane-based aqueous coating composition as used in Example 1, to which was added the same silane in the same amount as in Example 2, in addition to the wax Coupling agent and silica gel.
[0150] Table 4 shows the aver...
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