New type bone china, and producing method

A production method and technology of bone china, applied in the field of ceramics, can solve the problems of transparency effect, lack of raw materials of bone ash, reducing mechanical strength, etc., so as to improve mechanical strength and thermal stability, improve porcelain quality and delicate feeling, and reduce firing deformation. Effect

Inactive Publication Date: 2006-12-06
HUNAN XIANFENG CERAMIC IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Bone China is a kind of high-grade porcelain recognized in the world. It has the characteristics of fine porcelain, smooth, thin carcass, light weight, and good light transmission performance. There are following problems in its production process: 1, the thermal stability of product is poor
2. Because the structure of the composition of bone china in the fired body is close to the eutectic point of tricalcium phosphate, anorthite and silicic acid, the liquid phase content is large and the reaction is violent, so it is easy to deform, so it is advisable to adopt Buckle firing method, the existing mature technology can only use biscuit firing and then glaze firing twice, the sintering range is narrow, the firing is difficult to control, the authenticity rate is relatively low, energy waste is large, and the production cost is high
3. Lack of raw materials such as ashes
The amount of crystal phase in the porcelain body accounts for 50-70% (weight percentage), the quartz crystal grain is less than 25μm, and the main crystal phase is α-cristobalite, SiO 2 The ingredients are introduced with quartz and quartz glass powder. The invention mainly uses quartz glass powder to improve thermal stability, and uses wollastonite crystals to interweave needles in the porcelain body to improve the mechanical strength of the porcelain. Although the patent can once Burning still has the following defects: 1. It has been proved by prac

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0015] Example 1:

[0016] Ingredients: ashes: 10%, kaolin: 30%, porcelain stone: 52%, aluminum powder: 8% (weight percentage). The above-mentioned raw materials are mixed, ball milled, sieved, dehydrated, muddyed, formed, glaze applied, and fired (firing temperature 1230℃~1280℃, oxidizing flame firing) to obtain good light transmittance, strength and thermal stability The new bone china with good performance, smooth glaze and whiteness. After testing, the chemical composition of the body is: SiO2 54.5% Al2O3 26.3% P2O5 3.5% CaO 4.8% MgO 0.3% K2O+Na2O 3.6% Ignition loss 7%, porcelain body The amount of crystal phase is 60% (weight percentage), the main crystal phase is mullite, and the secondary crystal phase is β-Ca 3 (PO 4 O) 2 , Anorthite, feldspar glass accounted for 31% (weight percentage).

Example Embodiment

[0017] Example 2:

[0018] Ingredients: ashes: 6%, kaolin: 25%, porcelain stone: 60%, aluminum powder: 9% (weight percentage). According to the process described in Example 1, the firing temperature is 1240°C to 1300°C. After testing, the chemical composition of the body is: SiO2 56.2Al2O3 28.5% P2O5 2.1% CaO 2.9% MgO 0.2% K2O+Na2O 4.2% Ignition loss 5.9%, the amount of crystal phase in the porcelain body accounts for 65% (weight percentage), the main crystal phase It is mullite, the secondary crystal phase is β-Ca 3 (PO 4 O) 2 , Anorthite and feldspar glass account for 32% (weight percentage).

Example Embodiment

[0019] Example 3:

[0020] Ingredients: ashes: 8%, kaolin: 28%, porcelain stone: 55%, aluminum powder: 9% (weight percentage). According to the process described in Example 1, the firing temperature is 1240°C to 1300°C. After testing, the chemical composition of the green body is: SiO255.3% Al2O3 27% P2O5 2.8% CaO 3.9% MgO 0.4% K2O+Na2O 3.9% Ignition loss 6.7%. The amount of crystal phase in the porcelain body is 64% (weight percentage), the main crystal phase is mullite, and the secondary crystal phase is β-Ca 3 (PO 4 O) 2 , Anorthite and feldspar glass account for 34% (weight percentage).

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PUM

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Abstract

This invention relates to a method for manufacturing new type bone porcelain. The bone porcelain is composed of: SiO2 50-60 wt.%, Al2O3 20-30 wt.%, P2O5 1.8-3.5 wt.%, CaO 2-5 wt.%, MgO 0.2-0.5 wt.%, K2O and Na2O 3-5 wt.%. The crystal phase content is 50-70 wt. % in the porcelain body. The main crystal phase is mullite, and the minor crystal phases are beta-Ca3 (PO4)2 and anorthite. The bone porcelain is manufactured from: bone ashes 5-10 wt.%, Al powder 5-10 wt.%, kaolin 25-35 wt.%, and porcelain stone 45-60 wt.%. The bone porcelain has such advantages as good appearance, thin external wall, light weight, good light transmittance and good thermal stability. The title method has such advantages as low bon ashes addition, wide sintering range, high quality goods rate, low manufacturing cost and wide raw material resources, and is suitable for mass production.

Description

technical field [0001] The invention belongs to the technical field of ceramics, and relates to a novel bone china and a production method thereof. Background technique [0002] Bone China is a kind of high-grade porcelain recognized in the world. It has the characteristics of fine porcelain, smooth, thin carcass, light weight, and good light transmission performance. There are following problems in its production technology: 1, the thermal stability of product is poor. 2. Because the structure of the composition of bone china in the fired body is close to the eutectic point of tricalcium phosphate, anorthite and silicic acid, the liquid phase content is large and the reaction is violent, so it is easy to deform, so it is advisable to adopt For the buckle firing method, the existing mature technology can only use bisque firing and then glaze firing twice, the sintering range is narrow, the firing is difficult to control, the authenticity rate is relatively low, energy waste...

Claims

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Application Information

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IPC IPC(8): C04B35/185C04B35/622
Inventor 林迪辉周孝忠周胜武
Owner HUNAN XIANFENG CERAMIC IND
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