Electrophotographic toners containing polyalkylene wax or high crystallinity wax

a technology of polyalkylene wax and toner, applied in the field ofelectrophotographic toner, can solve the problems of wax affecting the triboelectric properties of toner, the toner is not as good in terms of toner ruboff, and the toner is not as good in terms of such properties as toner ruboff, so as to improve the abrasion resistance of the toner image

Inactive Publication Date: 2003-03-13
EASTMAN KODAK CO +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0005] A feature of the present invention is to provide an electrophotographic toner having improved toner image abrasion resistance.
[0007] A further feature of the present invention is to provide an electrophotographic toner formulation that reduces ruboff and yet provides satisfactory charge and / or flow properties.
[0010] The present invention also relates to a method of improving toner image abrasion resistance using the above-identified toner formulation of the present invention.

Problems solved by technology

The present toners, however, are not as good with respect to such properties as toner ruboff (e.g., the abrasion resistance of the fused image).
However, waxes can affect triboelectric properties of a toner.
This problem of increased triboelectric properties is more pronounced for negatively charging toners.
In addition, the toners may not be as free flowing as desired.
Furthermore, the presence of waxes can affect the glass transition temperature of the toner formulation and also can affect the release properties of a fused image from a heated fusing roller.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0053] A toner formulation was made from the following components:

1TABLE 1 Chemical Trade name Manufacturer Weight % Crosslinked styrene SB77XL Eastman Kodak 90.09 butyl acrylate copolymer Carbon Black Black Pearls 430 Cabot Corp 6.3 Polyethylene wax See Tables 2-4 Clariant or Baker 1.8 Petrolite Iron organic chelate T77 Hodogaya 1.8 charge control agent

[0054] The components were dry powder blended in a 40 liter Henschel mixer for 60 seconds at 1000 RPM to produce a homogeneous blend. The powder blend was then melt compounded in a twin screw co-rotating extruder to melt the polymer binder and disperse the pigments, charge agents, and waxes. Melt compounding was done at a temperature of 230.degree. F. at the extruder inlet, 230.degree. F. increasing to 385.degree. F. in the extruder compounding zones, and 385.degree. F. at the extruder die outlet. The processing conditions were a powder blend feed rate of 10 kg / hr and an extruder screw speed of 490 RPM. The cooled extrudate was then ...

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Abstract

Toner particles having at least one toner resin and at least one polyalkylene wax or a wax having a percent crystallinity of 80% or more are described. The wax that is present in the toner particles has a polydispersity of 2.0 or higher or a percent crystallinity of 80% or more, and also preferably has a number average molecular weight of about 2,000 or higher and / or a melting temperature onset of from about 115° C. to about 130° C. Development systems using the toner particles of the present invention are further described. Also, improvements in various properties associated with development systems are further described such as reduced toner dust levels as well as improved toner image abrasion resistance.

Description

[0001] This application claims the benefit under 35 U.S.C. .sctn.119(e) of prior U.S. Provisional Patent Application No. 60 / 317,289 filed Sep. 5, 2001, which is incorporated in its entirety by reference herein.[0002] The present invention relates to toners and development systems for toners.[0003] The image quality currently available with printers and copiers is generally good in that prints have a high solid area reflection density, low background in non-image areas, and consistent print quality from toner lot to toner lot and from the start of a new developer until it is replaced. The present toners, however, are not as good with respect to such properties as toner ruboff (e.g., the abrasion resistance of the fused image). In attempting to improve toner ruboff, a wax, for instance, can be included in the toner. However, waxes can affect triboelectric properties of a toner. This problem of increased triboelectric properties is more pronounced for negatively charging toners. If the...

Claims

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Application Information

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Patent Type & AuthorityApplications(United States)
IPC IPC(8): G03G9/083G03G9/087G03G9/08G03G9/097G03G15/08G03G15/09
CPCG03G9/0819G03G9/0821G03G9/08711G03G9/08782G03G9/08793G03G9/08795G03G9/08797G03G15/09
InventorFIELDS, ROBERT D.TYAGI, DINESH
OwnerEASTMAN KODAK CO