Polyurethane polishing pad

Inactive Publication Date: 2005-08-04
ROHM & HAAS ELECTRONICS MATERIALS CMP HLDG INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The fabrication of these semiconductor devices continues to become more complex due to requirements for devices with higher operating speeds, lower leakage currents and reduced power consumption.
The diminished physical properties, frequently associated with low k and ultra-low k materials, in combination with the devices' increased complexity have led to greater demands on CMP consumables, such as polishing pads and polishing solutions.
In particular, low k and ultra-low k dielectrics tend to have lower mechanical strength and poorer adhesion in comparison to conventional dielectrics, rendering planarization more difficult.
In addition, as integrat

Method used

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Examples

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examples

[0025] The following Table provides prepolymer and microsphere formulations for casting polyurethane cakes. These formulations contained various amounts of polymeric microspheres for producing porosity with different prepolymer formulations. These formulations tested toluene diiosocyanate [TDI] with polytetramethylene ether glycol [PTMEG], polypropylene ether glycol [PPG] and ester backbones from isocyanate-terminated prepolymers. As shown in following Tables, formulations 1 to 9 represent formulations of the invention and formulations A to E represent comparative examples. In particular, comparative example A corresponds to the formulation of Example 1 of U.S. Pat. No. 5,578,362; and comparative example B corresponds to the formulation of the IC1000™ polyurethane polishing pads sold by Rohm and Haas Electronic Materials CMP Technologies. The amount of NCO contained in the isocyanate-terminated prepolymers range from 5.3 to 9.11 percent.

TABLE 1Polishing Pad IngredientsEstimatedPol...

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Abstract

The polishing pad is suitable for planarizing at least one of semiconductor, optical and magnetic substrates. The polishing pad includes a cast polyurethane polymeric material formed with an isocyanate-terminated reaction product formed from a prepolymer reaction of a prepolymer polyol and a polyfunctional isocyanate. The isocyanate-terminated reaction product has 4.5 to 8.7 weight percent NCO reaction group; and the isocyanate-terminated reaction product is cured with a curative agent selected from the group comprising curative polyamines, curative polyols, curative alcoholamines and mixtures thereof. The polishing pad contains at least 0.1 volume percent filler or porosity.

Description

BACKGROUND [0001] This specification relates to polishing pads useful for polishing and planarizing substrates and particularly to polishing pads having uniform polishing properties. [0002] Polyurethane polishing pads are the primary pad-type for a variety of demanding precision polishing applications. These polyurethane polishing pads are effective for polishing silicon wafers, patterned wafers, flat panel displays and magnetic storage disks. In particular, polyurethane polishing pads provide the mechanical integrity and chemical resistance for most polishing operations used to fabricate integrated circuits. For example, polyurethane polishing pads have high strength for resisting tearing; abrasion resistance for avoiding wear problems during polishing; and stability for resisting attack by strong acidic and strong caustic polishing solutions. [0003] The production of semiconductors typically involves several chemical mechanical planarization (CMP) processes. In each CMP process, a...

Claims

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Application Information

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IPC IPC(8): B24B37/04C08G18/10C08G18/48
CPCB24B37/24C08G18/10C08G18/4854C08G18/3812C08G18/00
Inventor KULP, MARY JO
Owner ROHM & HAAS ELECTRONICS MATERIALS CMP HLDG INC
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