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Thermally-insulating layers and direct thermal imaging members containing same

a technology of thermal insulation layer and thermal imaging member, which is applied in the field of thermal imaging, can solve the problems of unwanted coloration, degraded performance, and introduced complexity into the process

Inactive Publication Date: 2012-04-05
ZINK IMAGING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This solution allows for independent control of each color-forming layer during printing, preventing unwanted coloration and maintaining image stability, thus simplifying the manufacturing process and improving the physical properties of the final product.

Problems solved by technology

Such migration of components may produce problems such as unwanted coloration in unprinted regions or changes in the activation temperature or degree of coloration of a color-forming layer, as is discussed in more detail below.
It is also possible that materials in adjoining layers may migrate into a color-forming layer and degrade its performance.
Such additional barrier layers introduce complexity into the process for manufacturing the thermal imaging member, and may also contribute undesirable physical properties to the final article, as discussed in detail below.

Method used

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  • Thermally-insulating layers and direct thermal imaging members containing same
  • Thermally-insulating layers and direct thermal imaging members containing same
  • Thermally-insulating layers and direct thermal imaging members containing same

Examples

Experimental program
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Effect test

example 1

[0142]This Example illustrates the thermal stability of an unprinted thermal imaging member of the present invention comprising a cyan color-forming layer in contact with a thermally-insulating layer of the present invention.

A coating fluid for a cyan color-forming layer was prepared by combining the materials shown in the table below in the proportions indicated:

Ingredient% solids in fluidCarboset 5262.61Zonyl FSN0.04Dispersion A3.55Dispersion E0.59Dispersion B2.67Dispersion F0.58

A coating fluid for a thermally-insulating layer (TI-1) of the present invention was prepared by combining the materials shown in the table below in the proportions indicated:

Ingredient% solids in fluidNEOCRYL A-616210Dispersion C2.35

Coatings were prepared as follows:

Coating A: Cyan color-forming layer was coated onto a filled, white, oriented polypropylene base of thickness 200 microns available from Yupo Corporation America, Chesapeake, Va. to a dried thickness of 4 g / m2.

Coating B: On top of and undernea...

example 2

[0143]This Example illustrates the thermal stability after printing of a thermal imaging member of the present invention comprising a cyan color-forming layer in contact with a thermally-insulating layer of the present invention.

A coating fluid for a cyan color-forming layer was prepared by combining the materials shown in the table below in the proportions indicated:

Ingredient% solids in fluidCP-6556.25Zonyl FSN0.056Dispersion A13.6Dispersion B3.72Dispersion E2.21Dispersion F2.16

Coating fluids for a thermally-insulating layers TI-2-TI-5 were prepared by combining the materials shown in the table below in the fluid % solids indicated:

TI-2TI-3TI-4TI-5CP65514.610.300PB6692MNA0014.610.3POVAL MP1032.32.32.32.3Dispersion D04.304.3Zonyl FSN0.060.060.060.06Alkanol XC0.050.050.050.05

A coating fluid for a thermally-resistant overcoat was prepared by combining the materials shown in the table below in the proportions indicated:

Ingredient% solids in fluidCarboset 5265.07POVAL MP1032.12Zonyl FS...

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Abstract

Multicolor thermal imaging members are described that comprise color-forming layers that are separated by thermally-insulating layers and can be addressed with a thermal printing head in contact with a surface to form an image. The thermally-insulating layers are designed to be as thin as possible consistent with at least partially independent addressing of the color-forming layers, and are formulated so as not to lead to instabilities either before or after printing or to give rise to dimensional changes of a thermal imaging member when it is subjected to changes in temperature or humidity. Coating compositions for manufacturing such thermally-insulating layers are also provided.

Description

REFERENCE TO RELATED APPLICATIONS[0001]This application is a continuation-in-part of copending U.S. patent application Ser. No. 11 / 397,251, filed on Jul. 23, 2002, entitled “Imaging System”, which is a continuation of U.S. patent application Ser. No. 10 / 806,749, filed on Mar. 23, 2004 issued as U.S. Pat. No. 7,166,558 which is a divisional of U.S. patent application Ser. No. 10 / 157,432, filed on May 20, 2002, issued as U.S. Pat. No. 6,801,233, which claims the benefit of prior U.S. provisional patent application Ser. Nos. 60 / 294,486, filed on May 30, 2001, and 60 / 364,198, filed on Mar. 13, 2002 the disclosures all of which are hereby incorporated by reference herein in their entirety.[0002]This application is related to the following commonly assigned United States patent applications and patents, the disclosures of all of which are hereby incorporated by reference herein in their entirety:[0003]U.S. Pat. No. 7,008,759 B2 which describes and claims color-forming compositions for use...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C09D129/04
CPCB41M5/34B41M5/423B41M5/44C08L21/02B41M2205/38B41M2205/28B41M2205/04B41M2205/42
Inventor DAY, JOHN C.HARDIN, JOHNHARDIN, YULINHASAN, FARIZA B.TELFER, STEPHENVETTERLING, WILLIAM T.
Owner ZINK IMAGING