Methionyl aminopeptidase inhibitor
A technology of methionyl aminopeptidase and thionyl aminopeptidase, which is applied in the field of a class of methionyl aminopeptidase inhibitors, can solve problems such as failure to achieve satisfactory results in life and health treatment, and achieve high Inhibiting activity, simple structure, and easy preparation
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[0038] The present invention will be further described below in conjunction with specific embodiments, but the present invention is not limited.
[0039] 1 H-NMR was measured with Varian MercuryAMX300 instrument; MS was measured with VG ZAB-HS or VG-7070 instrument, except for the EI source (70ev); all solvents were re-distilled before use. The water solvents are all obtained by drying according to standard methods; except for the instructions, all reactions are carried out under the protection of Ar gas and followed by TLC. The post-treatments are all washed with saturated brine and anhydrous MgSO 4 Drying process; except for instructions, the purification of the product uses silica gel (200-300 mesh) column chromatography; the silica gel used includes 200-300 mesh and GF 254 Produced by Qingdao Ocean Chemical Plant or Yantai Yuanbo Silicone Company.
[0040] 1. Preparation of compound 6
[0041]
[0042] Dissolve o-nitrobenzoyl chloride (5mmol) in dichloromethane (15ml), add 2...
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