Application of high molecular polymer emulsion film in protection film for fruit growth
A technology of high molecular polymer and high molecular emulsion, which is applied in the direction of protecting fruits/vegetables with a coating protective layer, which can solve the labor-intensive and time-consuming problems of fruit bagging, achieve pest erosion prevention, good ductility, and reduce labor intensity and cost effects
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Embodiment 1
[0023] In a four-necked flask equipped with a stirrer, a reflux condenser and a thermometer, add 45g of deionized water and 30g of an aqueous solution containing 1g of sodium bicarbonate, 1g of potassium persulfate and 1.5g of hydroxylamine, and raise the temperature to 60-82°C under stirring , dropwise added mixed monomers (ethyl acrylate 60g, acrylonitrile 6g, acrylic acid 3g) for 3h, and kept at 82-85°C for 2 hours. The temperature was lowered to 40° C., and 5 grams of surface-treated titanium dioxide was dispersed in the obtained emulsion under high-speed stirring. Add 2g of lime milk and 1g of copper sulfate, mix evenly, and filter the discharge. The prepared polymer emulsion is dip-coated or spray-coated on the young pome fruit in May to June to form a protective film.
Embodiment 2
[0025] (1) Add 5g of water and 15g of emulsifier solution (including one gram of OP-10 and one gram of AES) into the emulsifier, start stirring, slowly add 40g of butyl acrylate, 30g of styrene and 4g of acrylic acid, emulsify for about 15 minutes, stand-by.
[0026] (2) Add 40ml of deionized water into a four-neck flask (reactor) equipped with a stirrer, condenser, thermometer and feeder, and when the temperature rises to 85°C, add (1) emulsified monomer and Initiator solution (0.5 g of potassium persulfate, 0.5 g of disodium hydrogen phosphate, 30 g of deionized water) was dropped in about 90 minutes. Raise the temperature to 88°C for 1 hour.
[0027] (3) Cool down to 40° C., and disperse 5 grams of surface-treated titanium dioxide in the emulsion under high-speed stirring.
[0028] (4) Add 3g of milk of lime and 0.5g of copper sulfate, mix well and then discharge. The prepared polymer emulsion is dip-coated or spray-coated on young apples to form a protective film.
Embodiment 3
[0030] (1) Configuration of initiator solution: potassium persulfate 0.5g, disodium hydrogen phosphate 0.5g and deionized water 30g
[0031] (2) Configuration of emulsifier solution: AES 4g, OP-10 1g and water 40g
[0032] (3) Add 40ml of deionized water and prepared emulsifier solution into a four-necked flask (reactor) equipped with a stirrer, condenser, thermometer and feeder, and when the temperature is raised to 65°C, add 45g of VAc dropwise and 1 / 3 initiator solution, keep the temperature at 70°C for two hours, then raise the temperature to 82°C, add BA 40g and 1 / 3 initiator solution dropwise, for two hours, cool down to room temperature, add St 13g and stir to swell for 12 hours , heat up to 82°C, add 1 / 3 initiator solution, react for 3 hours, then cool down to 40°C.
[0033] (4) Disperse 5 grams of surface-treated titanium dioxide in the emulsion under high-speed stirring.
[0034] (5) Add 3g of milk of lime and 0.5g of copper sulfate, mix well and then discharge. T...
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