Direct oxidation fuel cell and method for making same
A fuel cell, direct technology, applied in the direction of fuel cells, fuel cell components, solid electrolyte fuel cells, etc., can solve the problems of increased fuel crossover effect, fuel utilization rate and power generation characteristics decline
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Embodiment approach 1
[0055] FIG. 1 is a schematic longitudinal sectional view showing the structure of a fuel cell according to an embodiment of the present invention. In this embodiment, the fuel cell is composed of one unit cell. The unit cell 10 includes a membrane electrode assembly (MEA) sandwiched between an anode-side separator 14 and a cathode-side separator 15 . The MEA includes a hydrogen ion conductor electrolyte membrane 11 and an anode 12 and a cathode 13 sandwiching the electrolyte membrane 11 . The anode-side separator 14 has flow channels 16 for supplying and discharging fuel to and from the anode side. The cathode-side separator 15 is provided with gas flow channels 17 for supplying and exhausting oxidant gas to and from the cathode side. Gaskets 18 and 19 are mounted on the periphery of the anode and cathode to sandwich the electrolyte membrane.
[0056] The unit cell 10 also includes current collector plates 20 and 21, heater plates 22 and 23, insulator plates 24 and 25, and ...
Embodiment 1
[0070] 30wt% platinum and 30wt% ruthenium with an average particle size of 30 Å were coated on carbon black (ketjen black EC, Mitsubishi Chemicals) with an average primary particle size of 30nm, namely conductive carbon particles, to prepare anode catalyst carrier particles. In addition, 50 wt % of platinum having an average particle size of 30 Å was coated on the same ketjen black EC to prepare cathode catalyst carrier particles. A dispersion of anode catalyst support particles or cathode catalyst support particles in an aqueous isopropanol solution and a polymer electrolyte dispersion in an aqueous solution of isopropanol were mixed together, and the mixture was highly dispersed using a ball mill. An anode catalyst slurry and a cathode catalyst slurry were prepared by this method. The weight ratio of catalyst support particles and polymer electrolyte in the catalyst slurry is 1:1. The polymer electrolyte employed was a perfluorocarbon sulfonate ionomer (Flemion, available f...
Embodiment 2
[0079] Fuel cell B was prepared in the same manufacturing method as in Example 1, except that the device in Fig. 3 was used for spray coating by adding deionized water to tetrafluoroethylene-hexafluoropropylene copolymer resin (ND-10E, A diluted solution (40 wt% FEP content) was prepared in a dispersion (available from Daikin Industries Co., Ltd.) to form a hydrophobic layer.
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