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High strength, high toughness a1-zn alloy product and method for producing such product

A high-strength, high-toughness technology, applied to high-strength, high-toughness Al-Zn alloys, the production of high-strength, high-toughness Al-Zn alloy products, alloy plate products, can solve stress corrosion resistance and fracture toughness, Strength loss and other issues, to achieve the effect of excellent performance

Active Publication Date: 2011-11-23
NOVELIS KOBLENZ GMBH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When artificially aged to T79, T76, T74, or T73-type tempers, their resistance to stress corrosion, exfoliation corrosion, and fracture toughness increase in the stated order (T73 is best, while T79 is close to T6), but with T6 temper conditions loss of strength compared to

Method used

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  • High strength, high toughness a1-zn alloy product and method for producing such product

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] On a laboratory scale, 14 different aluminum alloys were cast into ingots, homogenized, preheated at about 410 °C for more than 6 hours, and hot rolled into 4 mm plates. Solution heat treatment at 475°C followed by water quenching. Thereafter, the quenched product was aged by a two-step T76 aging process.

[0060] The chemical composition is listed in Table 1

[0061] Table 1 Chemical composition (% by weight) of the alloy in sheet form, the balance being aluminum and unavoidable impurities, Fe 0.06, Si 0.05, Ti 0.04 and Zr 0.12.

[0062] Alloy

Cu

Mg

Zn

other

1

2

3

4

5

6

7

8

9

10

11

12

13

14

2.0

2.1

1.7

2.1

2.4

1.7

2.1

2.4

1.7

2.1

2.5

2.1

2.1

2.1

2.1

2.1

1.75

1.7

1.7

2.2

2.1

2.1

2.5

2.4

2.5

2.1

2.1

2.1

8.0

8.1

8.7

...

Embodiment 2

[0084] Additional chemical compositions were processed according to processing steps 1-8 above, using variation 3 and T76 aging of step 5 of Example 1 above.

[0085] Table 3: Chemical composition (wt%) of the sheet alloys, for all alloys the balance is aluminum and unavoidable impurities, Fe 0.06, Si 0.05.

[0086] Alloy

[0087] To test the properties of the alloys in Table 3, the strength is tested in the L direction and the toughness is tested in the L-T direction.

[0088] Table 4: Strength and toughness (MPa) and notch toughness (TS / Rp) of the alloys shown in table 3, according to variant 3.

[0089] Alloy

[0090] The toughness and tensile yield strength (Rp) shown in Table 4 clearly shows that the best toughness and tensile yield strength values ​​are obtained for alloys with about 8.6-8.7 wt% zinc. Alloys with lower zinc levels showed similar toughness values ​​but lower (in general) tensile strength, whereas higher levels of zinc resulted in high...

Embodiment 3

[0092] Additional tests were performed for zinc levels of 8.6 and 8.7, varying copper and magnesium levels. It can be shown that the level of toughness can be increased at the same level of strength. Some additional alloys were processed similarly to Example 2, using the above processing steps 1-8 and variation 3 of Example 1 step 5.

[0093] Table 5. Chemical composition (wt%) of the sheet alloys, for all alloys the balance is aluminum and unavoidable impurities, Fe 0.06, Si 0.05.

[0094] Alloy

Cu

Mg

Zn

Zr

Ti

other

3

4

5

12

13

14

15

16

17

1.7

2.1

2.4

2.5

2.1

1.7

1.7

2.4

2.1

2.2

2.1

2.1

2.5

2.4

2.5

1.7

1.7

1.7

8.7

8.6

8.7

8.7

8.6

8.7

8.7

8.6

8.6

0.12

0.12

0.12

0.11

0.12

0.12

0.12

0.12

0.12

0.03

0.03

...

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Abstract

The invention relates to a Al-Zn alloy wrought product, and to a method of manufacturing such a product, with an improved combination of high toughness and high strength by maintaining good corrosion resistance, said alloy including (in weight percent): Zn 6.0-11.0, Cu 1.4-2.2, Mg 1.4-2.4, Zr 0.05-0.15, Ti < 0.05, Hf and / or V < 0.25, and optionally Sc and / or Ce 0.05-0.25, and Mn 0.05-0.12, other elements each less than 0.05 and less than 0.50 in total, balance aluminium, wherein such alloy has an essentially fully unrecrystallized microstructure at least at the position T / 10 of the finished product.

Description

field of invention [0001] The present invention relates to high-strength and high-toughness Al-Zn alloy deformed products, the alloy has an increased Zn content to maintain good corrosion resistance, and to a method of producing the high-strength and high-toughness Al-Zn alloy products and to the production of such alloys board products. More specifically, the present invention relates to high strength, high toughness Al-Zn alloys for structural aerospace applications and designated by the Aluminum Association International Nomenclature AA7000 series. More specifically, the present invention relates to a new chemical composition window for Al-Zn alloys with an improved combination of strength and toughness while maintaining good corrosion resistance, which does not require special aging or conditioning treatments. Background of the invention [0002] It is known in the art to use heat treatable aluminum alloys in many applications involving relatively high strength, high to...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C21/10C22F1/053
CPCC22F1/053C22C21/10
Inventor R·贝奈狄克图斯C·J·凯德尔A·L·海茵茨
Owner NOVELIS KOBLENZ GMBH