Electrolytic treatment device and electrolytic treatment method
A technology of electrolytic treatment and electrolyte, applied in the direction of electrolytic components, electrolytic process, etc., which can solve problems such as fracture, damage or deformation of electrical insulating plates, and poor conveyance of strips
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Embodiment approach 1
[0045] An example of the electrolytic treatment apparatus of the present invention, that is, an electrolytic roughening apparatus for roughening one surface of an aluminum web by an electrochemical method will be described.
[0046] [structure]
[0047] like figure 1 As shown, the electrolytic roughening device 100 of Embodiment 1 has: an electrolytic tank 1, which stores an acidic electrolyte solution inside, and transports the aluminum sheet W desired to be electrolytic roughened along the horizontal direction, and is a bottomed container with an open upper surface. A group of electrodes 2, which are arranged above the conveying path P of the aluminum sheet W inside the electrolytic cell 1; insulating plates 3, which are arranged below the conveying path P inside the electrolytic cell 1; guide rollers 4 , which guides the aluminum web W along the transport path P inside the electrolytic cell 1 .
[0048] Therefore, the insulating plate 3 is disposed on the opposite side of...
Embodiment 1~4
[0070] 1. Examples 1-4, Comparative Examples 1-3
[0071] use figure 1 In the electrolytic roughening device 100 of the shown form, an aluminum web is roughened by the electrolytic roughening device 100 . As the aluminum sheet, use pure aluminum with a thickness of 0.3mm and a width of 1000mm, the conveying speed is 50m / min, and the current density applied to each small electrode 2A of the electrode 2 is 75-125A / dm 2 , 60 Hz sine wave current, the target value of the surface roughness of the roughened surface was set to 0.5 μm, and electrolytic roughening was performed. As the acidic electrolytic solution, an aqueous hydrochloric acid solution having a concentration of 10 to 18 g / L is used.
[0072] In the electrolytic roughening device 100, the width of the electrode 2 is 1500 mm, and as the insulating plate 3, the following insulating plate is used, which is a non-scaling plate of polypropylene resin (specific gravity: 0.94) with a thickness of 15 mm and a width of 1200 mm...
Embodiment 5、6
[0080] 2. Embodiment 5, 6, reference example 1
[0081] As the insulating plate 3, the following insulating plate is used, which is a 15mm-thick polypropylene resin (specific gravity: 0.94) non-scaling plate, and the surface opposite to the electrode 2 is a flat surface (reference example 1), such as Figure 7 As shown, through-holes 34 are formed in a checkerboard pattern on the entire surface of the above-mentioned surface (Example 5), and as shown in FIG. Figure 8 As shown, grooves 35 in a direction perpendicular to the conveying direction a are formed (Example 6), and the distance between the aluminum sheet W and the insulating plate 3 is set to 0 mm. Electrolytic roughening of web W. In Example 5, the diameter of the through hole 34 was set to 5 mm, and the pitch in the direction parallel to and perpendicular to the conveyance direction a was set to 5 mm. In addition, in Example 6, the width of the groove 35 was set to 3 mm, and the pitch was set to 50 mm. The results...
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