Novel lithium ion battery electrolyte
A lithium-ion battery and electrolyte technology, which is applied in secondary batteries, circuits, electrical components, etc., can solve the problems of large gas production, unreasonable solvent formulation and ratio, and restricting the application range of lithium-ion batteries. Low temperature performance, the effect that meets the requirements
Active Publication Date: 2012-09-26
SHANSHAN ADVANCED MATERIALS QUZHOU CO LTD
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Problems solved by technology
[0003] However, due to factors such as the working temperature range of the lithium-ion battery electrolyte, its application range is limited. , the discharge capacity of the battery is only 62% of that at room temperature, and the discharge capacity at -40°C is less than 10% of that at room temperature; the electrolyte used in low temperature type produces a large amount of gas at a high temperature of 60°C, and the remaining capacity and recoverable capacity Less than 60%, which greatly limits the application range of lithium-ion batteries
[0004]The existing lithium-ion battery electrolyte is a mixture of the following carbonate organic solvents, such as: ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), vinylene carbonate (VC), fluoroethylene carbonate (FEC), ethyl acetate (EA ), fluorobenzene (FB), etc., each solvent has advantages and disadvantages, unreasonable solvent formula and ratio will affect the use temperature of lithium-ion battery electrolyte
Method used
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Effect test
Embodiment 1
[0027] In an argon-filled glove box (moisture 6 (the concentration of the lithium salt is 1 mol / L), and then stirred for 8 minutes to obtain the lithium ion battery electrolyte of the present invention.
Embodiment 2
[0029] In an argon-filled glove box (moisture 6 ) and 3% lithium bisoxalate borate (LiBOB) (the concentration of lithium salt is about 1.2mol / L), and then stirred for 15 minutes to obtain the lithium ion battery electrolyte of the present invention.
Embodiment 3
[0031] In an argon-filled glove box (moisture 6 ) and 3% lithium tetrafluoroborate LiBF 4 (The concentration of the lithium salt is about 1.2 mol / L), and then stirred for 10 minutes to obtain the electrolyte solution of the present invention.
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Abstract
The invention relates to the technical filed of battery electrolyte and particularly discloses novel lithium ion battery electrolyte. The lithium ion battery electrolyte can be prepared by adding an organic solvent mixed by acylester organic compounds in the general lithium ion battery electrolyte, adding 1-10 percent of addictive and chemically compounding with 8-15 percent of conductive lithiumsalt, wherein the addition amount of the acylester organic solvent is 75-90 percent of the weight of the lithium ion battery electrolyte. The lithium ion battery electrolyte can simultaneously meet the requirement of a lithium battery on the high-low temperature performances.
Description
technical field [0001] The invention relates to the technical field of battery electrolytes, and specifically discloses a novel lithium-ion battery electrolyte. Background technique [0002] As a new energy source, lithium-ion battery has attracted more and more people's attention, and has become one of the high-tech priorities, and is making important progress. Since the 1990s, due to its unique advantages such as high specific energy, high working voltage, wide application range, low self-discharge rate, long cycle life, no pollution, and good safety performance, it has been widely used as a home appliance Electrical appliances such as mobile phones, notebook computers, video cameras, cameras and other power supplies have gradually replaced traditional batteries in the fields of aviation, aerospace, navigation, artificial satellites, small medical instruments and military communication equipment. Therefore, lithium-ion batteries play an important role in modern electrochem...
Claims
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IPC IPC(8): H01M10/0567
CPCY02E60/12Y02E60/10
Inventor 侯涛王超
Owner SHANSHAN ADVANCED MATERIALS QUZHOU CO LTD
