A kind of anti-ultraviolet aging polyphenylene sulfide fiber and preparation method thereof

A polyphenylene sulfide fiber anti-ultraviolet aging technology, applied in fiber treatment, fiber chemical characteristics, stretch spinning, etc., can solve the problems of poor ultraviolet aging resistance of PPS fiber, achieve stable performance, cost saving, The effect of reducing the possibility of degradation

Inactive Publication Date: 2011-12-07
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The purpose of the present invention is to provide a kind of anti-ultraviolet aging polyphenylene sulfide fiber and its preparation method, to overcome the defect of existing PPS fiber not good anti-ultraviolet aging performance

Method used

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  • A kind of anti-ultraviolet aging polyphenylene sulfide fiber and preparation method thereof
  • A kind of anti-ultraviolet aging polyphenylene sulfide fiber and preparation method thereof
  • A kind of anti-ultraviolet aging polyphenylene sulfide fiber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] (1) Dissolve 60 parts of trichloro-s-triazine in dichloromethane, drop 100 parts of and 50 parts of AlCl 3 into the mixture, in N 2 Stirring continuously under the protection, keeping the temperature at about 25°C, after reacting for 2 hours, pour ice water to cool, AlCl 3 Reacts with water to form Al(OH) 3 , filter the suspension to remove aluminum hydroxide, then add 55 parts of in N 2 Continue to stir under the protection of the protection, keep the temperature at about 25 ° C, after 4 hours of reaction, remove the raw materials that have not participated in the reaction in the solvent, and then slowly evaporate the solvent to obtain 2-(3-N, N-diethylphenyl) Amino-4,6 bis(4-tert-butyl-2-hydroxyphenyl)-s-triazine;

[0051] Its molecular structure is

[0052]

[0053] (2) Dissolve 60 parts of trichloro-s-triazine in dichloromethane, drop 50 parts of 52 copies and 50 parts of AlCl 3 into the mixture, in N 2 Stirring continuously under the protection, ke...

Embodiment 2

[0063] (1) Dissolve 65 parts of trichloro-s-triazine in dichloromethane, drop 110 parts of and 55 parts of AlCl 3 into the mixture, in N 2 Stirring continuously under the protection, keeping the temperature at about 25°C, after reacting for 2 hours, pour ice water to cool, AlCl 3 Reacts with water to form Al(OH) 3 , filter the suspension to remove aluminum hydroxide, then add 60 parts of in N 2 Continue to stir under the protection of the protection, keep the temperature at about 25 ° C, after 4 hours of reaction, remove the raw materials that have not participated in the reaction in the solvent, and then slowly evaporate the solvent to obtain 2-(3-N, N-diethylphenyl) Amino-4,6 bis(4-tert-butyl-2-hydroxyphenyl)-s-triazine;

[0064] Its molecular structure is

[0065]

[0066] (2) Dissolve 65 parts of trichloro-s-triazine in dichloromethane, drop 55 parts of 56 copies and 55 parts of AlCl 3 into the mixture, in N 2 Stirring continuously under the protection, ke...

Embodiment 3

[0076] (1) Dissolve 62 parts of trichloro-s-triazine in dichloromethane, drop 106 parts of and 52 parts of AlCl 3 into the mixture, in N 2 Stirring continuously under the protection, keeping the temperature at about 25°C, after reacting for 2 hours, pour ice water to cool, AlCl 3 Reacts with water to form Al(OH) 3 , filter the suspension to remove aluminum hydroxide, then add 56 parts of in N 2 Continue to stir under the protection of the protection, keep the temperature at about 25 ° C, after 4 hours of reaction, remove the raw materials that have not participated in the reaction in the solvent, and then slowly evaporate the solvent to obtain 2-(3-N, N-diethylphenyl) Amino-4,6 bis(4-tert-butyl-2-hydroxyphenyl)-s-triazine;

[0077] Its molecular structure is

[0078]

[0079] (2) Dissolve 62 parts of trichloro-s-triazine in dichloromethane, drop 51 parts of 53 copies and 51 parts of AlCl 3 into the mixture, in N 2 Stirring continuously under the protection, ke...

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Abstract

The invention relates to ultraviolet-aging-resistant polyphenylene sulfide fibers and a preparation method thereof. The polyphenylene sulfide fibers comprise the following components in parts by weight: 100 parts of polyphenylene sulfide, 0.2-5 parts of 2-(3-N,N-diethyl-phenyl)amino-4,6-bis(4-tert-butyl-2-hydroxyphenyl)-sym-triazine and 0.2-5 parts of 2-ethylene imine-4-(2,2-dimethyl-4-tert-butyl)phenyl-6-(4-tert-butyl-2-hydroxy)-phenyl-triazine; and the fineness of the fibers is 1.2-6.6 dtex. The preparation method provided by the invention comprises the following steps of: adding polyphenylene sulfide, 2-(3-N,N-diethyl-phenyl)amino-4,6-bis(4-tert-butyl-2-hydroxyphenyl)-sym-triazine and 2-ethylene imine-4-(2,2-dimethyl-4-tert-butyl)phenyl-6-(4-tert-butyl-2-hydroxy)-phenyl-triazine to a screw spinning machine according to the proportions, carrying out melt spinning to obtain crude polyphenylene sulfide fibers, and then drawing and treating to obtain the fibers. The obtained fibers have greatly improved strength and modulus and excellent ultraviolet aging resistance.

Description

technical field [0001] The invention relates to an anti-ultraviolet aging polyphenylene sulfide (PPS) fiber and a preparation method thereof, specifically adding 2-(3-N,N-diethylphenyl)amino-4,6 bis(4 -tert-butyl-2-hydroxyphenyl)-s-triazine and 2-aziridine-4-(2,2-dimethyl-4-tert-butyl)benzene-6-(4-tert-butyl-2 A kind of anti-ultraviolet aging polyphenylene sulfide (PPS) fiber of -hydroxy) benzene triazine and preparation method thereof. Background technique [0002] The English name of polyphenylene sulfide Poly(phenylene sulfide) is referred to as PPS, and its chemical structure It is a thermoplastic crystalline resin with excellent comprehensive properties that was put on the market by the American Philips Petroleum Company in 1968 under the Ryton trademark and started industrial production in 1973. Its melting point is as high as 280-290°C and its decomposition temperature is greater than 400°C. The outstanding features of PPS engineering plastics are high temperature ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/94D01F1/10D01D5/088D01D5/12D01D10/00D01D10/02
Inventor 王依民甘海啸钦维民朱卫彪倪建华王燕萍
Owner DONGHUA UNIV
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