Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of hydrophobic nano mesoporous molecular sieve filling PDMC composite film

A mesoporous molecular sieve, hydrophobic nanotechnology, applied in chemical instruments and methods, membrane technology, semi-permeable membrane separation, etc., can solve problems such as poor swelling resistance and increasing physical cross-linking degree.

Active Publication Date: 2014-01-15
TSINGHUA UNIV
View PDF4 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, PDMS has poor swelling resistance in the MeOH / DMC azeotropic mixture. Generally, it is filled with inorganic particles to suppress the swelling of the membrane, especially filled with inorganic molecular sieves, which can not only increase the degree of physical crosslinking, but also provide channels for small molecules to pass through.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of hydrophobic nano mesoporous molecular sieve filling PDMC composite film
  • Preparation method of hydrophobic nano mesoporous molecular sieve filling PDMC composite film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Dissolve nano-mesoporous molecular sieve MCM-41 in toluene, prepare a solution with a mass concentration of 5%, stir and disperse, add octadecyltrichlorosilane with 50% mass of nano-mesoporous molecular sieve MCM-41, and stir at 50°C for 12h , filtered, washed with toluene, and dried at 300°C to obtain hydrophobic nano-mesoporous molecular sieve MCM-41; 10g RTV615-A, 1.5g RTV615-B were dissolved in 11.2g toluene, and then 5g of the above-mentioned hydrophobic nano-mesoporous molecular sieve was added Pore ​​molecular sieve MCM-41, stir well; scrape the film on the polysulfone (PS) porous bottom film, and dry it in an oven at 80°C for 10 hours to make it completely cross-linked to obtain a composite film. When the concentration of dimethyl carbonate in the feed liquid is 30wt%, the operating temperature is 40°C, and the absolute pressure behind the membrane is 400Pa, the separation factor of the above membrane is 3.88, and the permeation flux is 0.958kg / m 2 h.

Embodiment 2

[0032] Dissolve nanometer mesoporous molecular sieve MCM-48 in n-hexane, prepare a solution with a mass concentration of 15%, stir and disperse, add dropwise octyltrichlorosilane with 10% mass of mesoporous molecular sieve MCM-48, stir at 100°C for 6h, filter Finally, it was washed with n-hexane and dried at 100°C to obtain hydrophobic nano-mesoporous molecular sieve MCM-48; 5g of 107 type PDMS with a viscosity of 50000mpa s, 0.5g of crosslinking agent ethyl orthosilicate, 0.17g of catalyst II Dibutyltin laurate, dissolved in 24.9g of n-hexane, then add 5g of the above-mentioned hydrophobic nano-mesoporous molecular sieve MCM-48, stir evenly; scrape the film on the polyvinylidene fluoride (PVDF) porous bottom film, and keep it in an oven at 100°C Dry it for 8 hours to make it completely cross-linked to obtain a composite membrane. When the concentration of dimethyl carbonate in the feed liquid is 30wt%, the operating temperature is 40°C, and the absolute pressure behind the me...

Embodiment 3

[0034]Dissolve nano-mesoporous molecular sieve MCM-41 in cyclohexane, prepare a solution with a mass concentration of 30%, stir and disperse, add dodecamethyltrichlorosilane with a mass of nano-mesoporous molecular sieve MCM-41 of 30%, at 70°C Stir for 36 hours, filter, wash with cyclohexane, and dry at 200°C to obtain hydrophobic nano-mesoporous molecular sieve MCM-41; mix 10g of 108-type PDMS with a viscosity of 10000mpa s, 1g of cross-linking agent phenyltrimethoxysilane , 0.33g of catalyst dibutyltin dilaurate, dissolved in 17.75g of n-heptane, then add 0.5g of the above-mentioned hydrophobic nano-mesoporous molecular sieve MCM-41, stir evenly; , and kept in an oven at 120°C for 4 hours to make it completely cross-linked to obtain a composite film. When the concentration of dimethyl carbonate in the feed liquid is 30wt%, the operating temperature is 40°C, and the absolute pressure behind the membrane is 400Pa, the separation factor of the above membrane is 3.38, and the pe...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
separation factoraaaaaaaaaa
separation factoraaaaaaaaaa
separation factoraaaaaaaaaa
Login to View More

Abstract

The invention discloses a preparation method of a hydrophobic nano mesoporous molecular sieve filling PDMC composite film, comprising the following steps: using a casting solution containing polydimethylsiloxane (PDMS), hydrophobic mesoporous molecular sieve, cross-linking agent, catalyst, and solvent to wipe film on the upper layer of a porous ultrafiltration membrane supported by polyester non-woven, and heating until crosslinking completely to obtain the composite film. The obtained mesoporous molecular sieve modified by surface silane coupling agent is combined with the PDMS substrate tightly, and is dispersed uniformly in the PDMS substrate. The preparation method has the advantages of simple process and cheap selected materials. The composite film has strong swelling resistance in dimethyl carbonate(DMC) / methanol azeotrope, and excellent DMC permselective property. When the filling weight ratio of the mesoporous molecular sieve is 30 %, the separation factor alfa is 4.07, the penetration flux J is 1.13 kg / m<2>h([DMC]=30 wt%, 40 DEG C).

Description

technical field [0001] The invention relates to the technical field of pervaporation membrane separation, in particular to a method for preparing a hydrophobic nanometer mesoporous molecular sieve filled PDMS composite membrane which can be used for pervaporation separation of dimethyl carbonate / methanol azeotropic liquid. Background technique [0002] Dimethyl carbonate (DMC) is an environmentally friendly chemical. It can replace phosgene, dimethyl sulfate, etc. as a methylating agent and carbonylating agent to synthesize a variety of green high-tech fine chemicals. At the same time, as a green and low-toxic solvent, it is widely used in coatings, medicine, pesticides and other industries. The industrial production of DMC obtains methanol (MeOH) / DMC azeotropic mixture, and under normal pressure, the mass fraction of DMC in the azeotrope is 30%. The high energy consumption required for separation by the pressure distillation method greatly increases the production cost of...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): B01D71/70B01D69/12B01D67/00
Inventor 李继定王蕾郑冬菊秦琳陈剑
Owner TSINGHUA UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com