Compounds containing 1,2-difluoroethylene and difluoromethylene ether structure, and preparation and application thereof
A technology of difluoromethylene ether and vinylidene fluoride, which is applied to compounds containing 1,2-difluoroethylene and difluoromethylene ether structures and their preparation and application fields, can solve the problem of low threshold voltage, liquid crystal materials Users are not satisfied, performance is not suitable for market development, etc.
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[0082] Example 1
[0083] A method for preparing the above-mentioned compound containing 1,2-difluoroethylene and difluoromethylene ether structure, and its synthetic route is in figure 1 Means in. The specific process steps of compound I-2-1 prepared according to the above synthetic route are as follows:
[0084]
[0085] 1) Synthesis of p-bromobenzenetrifluoroethylene
[0086] a. Add 57.7ml of diisopropylamine, 180ml of THF, nitrogen protection to a 250ml single-necked flask, cool the ethanol bath to -20°C, control the temperature from 0 to -20°C, add 160ml n-BuLi dropwise, after dripping, stir at 0 to -20°C In 1 hour, 1mol / L LDA 0.4mol was prepared for use.
[0087] b. Add 27.2g of anhydrous zinc chloride, 100ml of THF, nitrogen protection to a 1000ml three-necked flask, cool the ethanol bath to -50°C, and pass 20.4g of CF 3 CH 2 F. Slowly inject the above 0.4mol LDA under the liquid surface with a temperature-controlled needle tube from -40 to -50°C, stir for 2 hours after the ad...
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[0109] Example 2
[0110] The compounds and parts by weight listed in Table 2 are formulated into the liquid crystal composition of the invention, which is filled between the two substrates of the liquid crystal display for performance testing. The test data are also listed in Table 2.
[0111] Table 2. Components and parts by weight of Example 2
[0112]
[0113] The following conclusions can be drawn from the control example and example 2:
[0114] Using the compound contained in the general formula I of the present invention, the refractive index of Example 2 is significantly improved compared with the control example, and it can be used in a thinner cell, thereby obtaining a shorter response time;
[0115] Using the compound contained in the general formula I of the present invention, the rotational viscosity of Example 2 has a certain degree of decrease compared with the control example, thereby obtaining a shorter response time;
[0116] Using the compound contained in the general ...
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