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Energy ray-curable epoxy resin composition having excellent curing properties in deep portions

A technology of energy ray curing and epoxy resin, which is applied in the direction of epoxy resin glue, adhesive type, hydrocarbon copolymer adhesive, etc., can solve the problem of poor deep curing of epoxy resin, and improve the deep curing , the effect of high fixed precision

Active Publication Date: 2014-11-26
KYORITSU KAGAKU SANGYO KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, cationic curable epoxy resins have a problem of poor deep curability

Method used

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  • Energy ray-curable epoxy resin composition having excellent curing properties in deep portions
  • Energy ray-curable epoxy resin composition having excellent curing properties in deep portions
  • Energy ray-curable epoxy resin composition having excellent curing properties in deep portions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 and comparative example 1～2

[0041] Based on the proportions recorded in Table 1, dissolve the photoacid generator PI2074 in 4-butyrolactone, add it to EPICLON 850 and CEL3000, stir until transparent, and prepare the energy ray-curable epoxy resin combination of Comparative Example 1 thing.

[0042] Based on the compounding ratio shown in Table 1, GS350T or GS310T was added to the epoxy resin composition of Comparative Example 1 and stirred until uniform, thereby preparing the energy ray-curable epoxy resin composition of Example 1 or Comparative Example 2.

[0043] The deep curability of the epoxy resin compositions of Example 1 and Comparative Examples 1 and 2 was measured. Deep cure is determined as follows: In the clarinet tube of the hole, the energy ray-curable epoxy resin compositions of Example 1 and Comparative Example 1 and 2 were filled with a height of 5 mm, and the UV irradiation machine made by Hamamatsu Photonics was used from the top at 500 mW / cm 2 (365nm) irradiation for 10 seconds, ta...

Embodiment 2 and comparative example 3

[0054] Based on the compounding ratio described in Table 2, the epoxy resin compositions of Example 2, Comparative Examples 3 and 4 were prepared. The deep curability of each epoxy resin composition was measured. The results are shown in Table 2.

[0055] [Table 2]

[0056] Product Number

Example 2

Comparative example 3

Comparative example 4

EPICL0N 860

45

45

45

OXT-211

15

15

15

OXT-121

5

5

5

OXT-191

5

5

5

PI2074

3

3

3

DETX-S

0.01

0.01

0.01

CPI-210S

Art Pearl GS-350T (refractive index 1.55)

45

TALC P-2 (refractive index 1.58)

20

45

Refractive index of resin composition without filler

1.55

155

1.55

Deep curability 500mW / cm 2 ×10s

2.7mm

1.9mm

1.4mm

[0057] EPICLON 860: Bisphenol A type epoxy re...

Embodiment 3 and comparative example 5

[0067] Based on the formulations described in Table 3, the epoxy resin compositions of Example 3 and Comparative Example 5 were prepared. The deep curability of each epoxy resin composition was measured. The results are shown in Table 3.

[0068] [table 3]

[0069]

Example 3

Comparative Example 5

YX8034

45

45

OXT-211

30

30

OXT-191

5

5

CPI-210S

2

2

Art Pearl GS-310T (refractive index 1.51)

32.5

Art Pearl GS-350T (refractive index 1.55)

325

Refractive index of resin composition without filler

1.51

1.51

Deep hardening 500mW / cm 2 ×10s

3.3mm

1.7mm

[0070] YX8034: hydrogenated bisphenol A type epoxy resin: jER company (Japan Epoxy Resins)

[0071] OXT-211: 3-ethyl-3-(phenoxymethyl)oxetane (manufactured by Toagosei Co., Ltd.)

[0072] OXT-191: Oxetanyl silicate (manufactured by Toagosei Co., Ltd.)

[0073] CPI-2...

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Abstract

Disclosed is an energy ray-curable epoxy resin composition wherein the problem of poor curing properties in deep portions has been solved, while maintaining high fixation accuracy. Specifically disclosed is an energy ray-curable epoxy resin composition containing an epoxy resin, a filler and a photoacid generator, wherein the difference between the refractive index of the filler and the refractive index of the energy ray-curable epoxy resin composition excluding the filler is within ±0.02.

Description

technical field [0001] The present invention relates to an energy ray-curable epoxy resin composition, and more particularly to an energy ray-curable epoxy resin composition for fixing optical components having excellent deep curability while maintaining high fixing accuracy. Background technique [0002] In an optical pickup device, a photocurable adhesive is used to fix a photodetector to a housing (Patent Documents 1 and 2). This adhesive is required to have high fixing accuracy and high deep curability. [0003] The fixing accuracy refers to the accuracy showing that the photodetector does not move from a predetermined position when the photodetector is fixed to the case. If the fixing accuracy is too low, the photodetector will move from a predetermined position during manufacture of the optical pickup device or after an endurance test, and photodetection will not be possible. Therefore, high fixing accuracy is required. [0004] The deep curability is an index showi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L63/00C08G59/68C08K5/1525C09J125/08C09J133/00C09J163/00
CPCC09J163/00C08K5/1525C08L33/08C08L25/08C08G59/68C08L2666/04
Inventor 远山茂树
Owner KYORITSU KAGAKU SANGYO KK
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