Mixed resin capable of producing derma effects and used for synthetic leather and preparation method thereof

A technology of mixing resin and synthetic leather, applied in textiles and papermaking, etc., can solve the problems that affect the color display of mixed resin, the effect of force discoloration is not obvious, and the stress distribution cannot be equal.

Active Publication Date: 2012-06-13
ZHEJIANG SUNLIGHT MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The prior art uses color-changing wax powders such as silicon dioxide and hydroxyorganosilicon, because they cannot produce the effect of stress phase separation, so the effect of changing color under force is not obvious
And if silicon dioxide wax is used, because silicon dioxide is an inorganic material and has hiding power, it will affect the display of other colors in the mixed resin;

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A mixed resin for synthetic leather capable of producing dermis effect, its composition is as follows by weight percentage:

[0030] Alcohol-soluble acrylate resin: 8%

[0031] Alcohol-soluble polyurethane resin: 20%

[0032] Micronized polypropylene wax: 2%

[0033] Fluff powder: 6%

[0034] Fatty alcohol polyoxyethylene ether: 5%

[0035] Silicone slip agent: 0.5%

[0036] n-Butanol: 20%

[0037] The balance is diacetone alcohol: 38.5%.

[0038] Preparation method: Sand mill production:

[0039] 1: Add 20KG of n-butanol, 38.5KG of diacetone alcohol, 0.5KG of silicone slip agent, 5KG of fatty alcohol polyoxyethylene ether, add 20KG of alcohol-soluble aliphatic polyurethane resin slurry while stirring, stir and mix uniform, forming an infiltrate;

[0040] 2: Add 8KG of alcohol-soluble acrylate resin powder and 6KG of fluff powder while stirring, and stir for 30 minutes at a stirring speed of 1500 rpm;

[0041] 3: Add 2KG of micronized polypropylene wax while st...

Embodiment 2

[0044] A mixed resin for synthetic leather capable of producing dermis effect, its composition is as follows by weight percentage:

[0045] Alcohol-soluble acrylate resin: 7%

[0046] Alcohol-soluble polyurethane resin: 30%

[0047] Micronized polypropylene wax: 3%

[0048] Fluff powder: 5%

[0049] Fatty alcohol polyoxyethylene ether: 4%

[0050] Silicone slip agent: 1%

[0051] n-Butanol: 40%

[0052] The balance is diacetone alcohol: 10%.

[0053] Preparation method: Sand mill production:

[0054] 1: Add 40KG of n-butanol, 10KG of diacetone alcohol, 1KG of silicone slip agent, 4KG of fatty alcohol polyoxyethylene ether, add 30KG of alcohol-soluble aliphatic polyurethane resin slurry while stirring, stir and mix evenly, to form an infiltrate;

[0055] 2: Add 7KG of alcohol-soluble acrylate resin powder and 5KG of fluff powder while stirring, and stir for 30 minutes at a stirring speed of 1500 rpm;

[0056] 3: Add 3KG of micronized polypropylene wax while stirring, k...

Embodiment 3

[0059] A mixed resin for synthetic leather capable of producing dermis effect, its composition is as follows by weight percentage:

[0060] Alcohol-soluble acrylate resin: 6%

[0061] Alcohol-soluble polyurethane resin: 35%

[0062] Micronized polypropylene wax: 3%

[0063] Fluff powder: 5%

[0064] Fatty alcohol polyoxyethylene ether: 4%

[0065] Silicone slip agent: 1%

[0066] n-Butanol: 25%

[0067] The balance is diacetone alcohol: 21%.

[0068] Preparation method: Sand mill production:

[0069] 1: Add 25KG of n-butanol, 21KG of diacetone alcohol, 1KG of silicone slip agent, 4KG of fatty alcohol polyoxyethylene ether, add 35KG of alcohol-soluble aliphatic polyurethane resin slurry while stirring, stir and mix evenly, formation of an infiltrate;

[0070]2: Add 6KG of alcohol-soluble acrylate resin powder and 5KG of fluff powder while stirring, and stir for 30 minutes at a stirring speed of 1500 rpm;

[0071] 3: Add 3KG of micronized polypropylene wax while stirrin...

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Abstract

The invention relates to a mixed resin used for synthetic leather and a preparation method thereof. The mixed resin capable of producing derma effects and used for the synthetic leather comprises, by weight, the alcohol soluble acrylate resin 2-8%, the alcohol soluble polyurethane resin 20-60%, the micronization plypropylene wax 2-6%, the tomentum powder 2-6%, the fatty alcohol-polyoxyethylene ether 2-5%, the organosilicon slip agent 0.5-3%, the n-butyl alcohol 10-40% and the balance diacetone alcohol. The synthetic leather manufactured by using the mixed resin has characteristics similar to the derma such as feel of fur of animals, produced natural fissures after being stressed and occurred natural color changing after being pulled, occurred repristination after external force disappears. The mixed resin adopts alcohol as solvent, so that environmental effects caused by solvent such as toluene and dimethylformamide in a productive process of the synthetic leather are reduced.

Description

technical field [0001] The invention relates to a mixed resin for synthetic leather and a preparation method thereof. Background technique [0002] Ordinary synthetic leather resins are all polyurethane resins, which cannot produce genuine leather effects such as wool, cracks, and natural discoloration. However, synthetic leather products have always pursued similarity or surpassing genuine leather in terms of function and style. Existing artificial leather effect resins for synthetic leather, animal hair feeling, cracks and discoloration effects can not be similar to real leather. [0003] The main disadvantages of the prior art are: [0004] 1) In terms of animal hair feeling: only polyurethane resin is used as the carrier resin in the mixed resin of the prior art. The polyurethane resin has strong adhesion and flexibility, so it is difficult to reveal the fluff in the mixed resin that can reflect the fur feeling of real fur, even by rubbing; [0005] 2) In terms of dis...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L33/04C08L23/12C08K5/54D06N3/14
Inventor 朱建琴郦向宇余苏文戴文琪
Owner ZHEJIANG SUNLIGHT MATERIAL TECH CO LTD
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