Novel tolyltriazole complex efficient fluorescent crystal material and preparation method thereof

A technology of copper triazole and fluorescent crystals, which is applied in luminescent materials, copper organic compounds, chemical instruments and methods, etc., can solve the problems of environmental pollution, high cost, harsh preparation conditions, etc., and achieves good photostability and low cost. , the effect of high luminous efficiency

Active Publication Date: 2012-06-20
见喜纳米材料技术研发(河南)有限公司
View PDF0 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since most crystal luminescent materials are prepared by high-temperature pulling method or molten salt method, ...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Novel tolyltriazole complex efficient fluorescent crystal material and preparation method thereof
  • Novel tolyltriazole complex efficient fluorescent crystal material and preparation method thereof
  • Novel tolyltriazole complex efficient fluorescent crystal material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0019] Example 1: (1) Weigh 200.0 mg CuI, 40.0 mg 2,5-bis(3-pyridine)-1,3,4-oxadiazole, add 1 ml 25% ammonia water and 10 ml deionized water to 15 ml In an autoclave, and stirred at room temperature for 5 h to obtain a mixed solution. The mixed solution was heated at 180 °C for 72 h, then at 3 °C h -1 Cool down to room temperature at a cooling rate. After the obtained precipitate was washed with water several times, yellow blocky crystals were obtained. The yield was calculated to be 52.5% based on the CuI used. Bright yellow luminescence can be seen when irradiated with a 4W hand-held fluorescent light.

[0020] (2) Weigh 300.0 mg CuI, 20.0 mg 2,5-bis(3-pyridine)-1,3,4-oxadiazole, 10 ml 25% ammonia water and 24 ml deionized water into a 50 ml autoclave and stirred at room temperature for 15 h to obtain a mixed solution. The mixed solution was heated at 80 °C for 120 h, then at 2 °C h -1 Cool down to room temperature at a cooling rate. After the obtained precipitate was...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a novel tolyltriazole complex efficient fluorescent crystal material and a preparation method thereof, and relates to the preparation of efficient fluorescent crystal materials. The novel tolyltriazole complex efficient fluorescent crystal material comprises [Cu3(3,5-bi(3-pyridine)-1,2,4-tolyltriazole)I2]n. 3,5-bi(3-pyridine)-1,2,4-tolyltriazole generated by a ring conversion reaction of 2,5-bi(3-pyridine)-1,3,4-oxadiazole is used as a ligand, and a stable [Cu3(3,5-bi(3-pyridine)-1,2,4-tolyltriazole)I2]n crystal material with high luminous efficiency is prepared by a mild hydrothermal method. The single crystal property, the thermal stability and the efficient luminous property of a luminous crystal material are described by X-ray single crystal diffraction, X-ray powder diffraction, an infrared absorption spectrum, a thermogravimetric curve, an excitation spectrum, an emission spectrum, an absorption spectrum and the like. The obtained crystal material can emit bright yellow light under the irradiation action of a fluorescent lamp.

Description

technical field [0001] The invention relates to a high-efficiency luminescent crystal material and a preparation method thereof, in particular to a triazole copper complex crystal luminescent material and a preparation method thereof. [0002] Background technique [0003] With the depletion of fossil energy, the energy crisis is approaching. While developing renewable energy, improving the utilization rate of energy has also attracted great attention from all over the world. Currently, lighting consumes more than 50% of the world's total power generation. In order to effectively improve energy utilization efficiency, high-efficiency luminescent materials that have high energy conversion efficiency and can effectively avoid the high energy loss in conventional luminescent materials have attracted more and more attention from the scientific and commercial communities. To achieve a higher quantum yield of luminescent materials, optical materials must be able to convert the ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C07F1/08C09K11/06
Inventor 卢灿忠房贞兰余荣民吴小圆
Owner 见喜纳米材料技术研发(河南)有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap