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Polarizing plate and liquid crystal display including the polarizing plate

A technology of polarizing plates and polarizers, which is applied in the field of polarizing plates and liquid crystal displays (LCDs), and can solve the problems of redness of polarizing plates

Active Publication Date: 2015-07-29
CHEIL IND INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, an excess of zirconium in the adhesive can cause red discoloration of the polarizing plate.

Method used

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  • Polarizing plate and liquid crystal display including the polarizing plate
  • Polarizing plate and liquid crystal display including the polarizing plate

Examples

Experimental program
Comparison scheme
Effect test

preparation example

[0054] A polyvinyl alcohol film (thickness: 75 μm, degree of polarization: 2400, degree of saponification: 99% or higher) was swollen in an aqueous solution at 25 °C and dyed in a dyeing solution at 30 °C in a dyeing bath. Then, the dyed polyvinyl alcohol film was stretched in a boric acid aqueous solution at 55° C., thereby preparing a polyvinyl alcohol film having a final elongation 6 times its initial elongation. Then, the polyvinyl alcohol film was dried in a chamber at 50 °C for 3 min to prepare a 20 μm thick polarizer.

[0055] Components used in Examples and Comparative Examples are described below.

[0056] For convenience of description, the protective film adhered above the polarizer is called "first protective film", and the protective film adhered under the polarizer and placed on the liquid crystal panel is called "second protective film".

[0057] (A) Polarizer: The polarizer manufactured by the Example was used;

[0058] (B) Protective film:

[0059] (b1) Fir...

Embodiment 1-4

[0066] An aqueous adhesive having the components listed in Table 1 (by weight) based on 100 parts by weight of water was prepared. Each aqueous adhesive was applied to both sides of the polarizer prepared in Preparation Example. The first protective film was laminated on the upper side of the polarizer and the second protective film was laminated on the lower side of the polarizer, and the first protective film and the second protective film were combined with the polarizer using a roll laminator. The combined product was cured at 85° C. for 1 hour, thereby preparing a polarizing plate.

experiment example

[0072] The physical properties of the polarizing plates of Examples and Comparative Examples were evaluated, and the evaluation results are shown in Table 2.

[0073] (1) Change of light transmittance after immersion test: each polarizing plate (thickness: 162 μm, adhesive layer thickness: 1 μm) was adhered to an alkali-free glass plate (2cm×4cm), and the prepared samples were fixed in a fixture superior. The light transmittance value of each sample was measured at a wavelength of 400 to 780 nm at a wavelength interval of 2 nm using a spectrophotometer (V-7100, Jasco Co., Ltd.), and the measured light transmittance values ​​were averaged (value A) . Then, the polarizing plate sample was immersed in water at about 25° C. for about 3 hours, followed by drying at about 25° C. for about 2 hours. Then, the average value B of light transmittance was measured in the same method. Finally, the change in transmittance is calculated using |B-A|.

[0074] (2) Change of polarization de...

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Abstract

A polarizing plate includes a polarizer; and a protective film attached to at least one side of the polarizer via an adhesive layer. The adhesive layer is formed of a water-based adhesive including a polyvinyl alcohol resin, a zirconium compound, and an imine crosslinking agent. The polarizing plate has a variation in light transmittance (|B−A|) from 0% to about 0.25% at wavelengths from 400 nm to 780 nm, where A is an average value of initial light transmittance of the polarizing plate at wavelengths from 400 nm to 780 nm, and B is an average value of light transmittance of the polarizing plate at wavelengths from 400 nm to 780 nm measured after the polarizing plate has been dipped in water of 25° C. for 3 hours, followed by drying at 25° C. for 2 hours.

Description

technical field [0001] The present invention relates to a polarizing plate and a liquid crystal display (LCD) including the polarizing plate. More particularly, the present invention relates to a polarizing plate having a small change in optical characteristics including light transmittance and / or polarization degree, thereby providing an LCD under heat and humidity conditions, and an LCD including the same. High durability and resistance and improved adhesion. Background technique [0002] In order to display the display pattern of the liquid crystal display, polarizing plates are placed on both sides of the liquid crystal cell to control light oscillation. Applications of liquid crystal displays have continuously expanded from small devices at the initial stage to notebook computers, LCD monitors, LCD color projectors, LCD TVs, car navigation systems, personal phones, outdoor / indoor measuring instruments, and the like. In particular, in some applications such as LCD disp...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G02B5/30G02B1/14G02F1/1335B32B27/08B32B27/30
CPCY10T428/1059Y10T428/1041B32B27/306G02B5/3025C09J129/04B32B27/08B32B27/30Y10T428/2878G02F1/133533C09K2323/031C09K2323/05G02B5/30G02F1/1335
Inventor 徐银卿申东允金爱卿曺芽罗俞素熙白一雄金旼晶郑海龙
Owner CHEIL IND INC