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Functionalization of organic molecules using metal-organic frameworks (mofs) as catalysts

A technology of metal-organic frameworks and organic molecules, applied in the preparation of organic compounds, organic compound/hydride/coordination complex catalysts, 5/15 group organic compounds without C-metal bonds, etc. problems such as over-oxidation

Inactive Publication Date: 2013-10-09
RGT UNIV OF CALIFORNIA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the selective oxygen functionalization of hydrocarbons remains a major challenge for contemporary chemistry
Many of the chemistries used to oxidize alkanes require stringent conditions of temperature or pressure, and the reactants are prone to over-oxidation, resulting in a range of products, many of which are undesirable

Method used

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  • Functionalization of organic molecules using metal-organic frameworks (mofs) as catalysts
  • Functionalization of organic molecules using metal-organic frameworks (mofs) as catalysts
  • Functionalization of organic molecules using metal-organic frameworks (mofs) as catalysts

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Embodiment Construction

[0056] As used herein and in the appended claims, the singular forms "a", "an" and "the" include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to "a framework" includes a plurality of such frameworks and reference to "the metal" includes reference to one or more metals and their equivalents known to those skilled in the art, and so on.

[0057] Unless otherwise defined, all scientific and technical terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. Although many methods and reagents similar or equivalent to those described herein can be used in the practice of the disclosed methods and compositions, exemplary methods and materials are disclosed herein.

[0058] Also, the use of "and" means "and / or" unless stated otherwise. Similarly, "comprising" and "including" are used interchangeably and are not intended to be limiting.

[0059]It should be fur...

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Abstract

The disclosure provides for catalytic multivariate metal organic frameworks and methods of use thereof.

Description

[0001] Cross References to Related Applications [0002] This application claims priority under 35 U.S.C. §119 to Provisional Application No. 61 / 365,901, filed July 20, 2010, the disclosure of which is incorporated herein by reference in its entirety. technical field [0003] The present disclosure provides organic frameworks for use in catalyzing the functionalization of organic molecules. Background technique [0004] The oxidation of alkanes is of great practical importance and can provide valuable intermediates for chemical synthesis. However, the selective oxygen functionalization of hydrocarbons remains a major challenge for contemporary chemistry. Many of the chemistries used to oxidize alkanes require severe conditions of temperature or pressure, and the reactants are prone to over-oxidation, producing a range of products, many of which are undesirable. Furthermore, other methods for functionalizing hydrocarbons require the use of environmentally harmful reagents,...

Claims

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Application Information

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IPC IPC(8): C07F9/00C07F15/00B01J31/02
CPCB01J31/02C07C51/16C01B39/00C07F9/005B01J31/1691B01J31/183B01J31/2239B01J2231/321B01J2531/56C07C51/145C07C51/305Y02P20/582C07C53/122C07C53/08C07F1/00C07F9/00C07F15/00
Inventor 奥玛尔·M·亚纪A·U·科扎亚A·T·P·潘
Owner RGT UNIV OF CALIFORNIA
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