Nonoriented electromagnetic steel sheet
An electromagnetic steel plate and non-directional technology, applied in the direction of inorganic materials, circuits, magnetic materials, etc., can solve the problems of iron loss degradation and achieve excellent iron loss effect
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Embodiment 1)
[0056] First, a hot-rolled sheet containing C: 0.002% by mass, S: 0.002% by mass, N: 0.002% by mass, and Mn: 0.3% by mass, Si, Al, and Cr having the composition shown in Table 1 below was prepared and pickled. A cold-rolled sheet having a thickness of 0.25 mm was obtained by cold rolling. Next, the oxygen potential was controlled under the conditions shown in Table 1, and finish annealing was performed at 1000° C. to obtain a non-oriented electrical steel sheet.
[0057] Table 1
[0058]
[0059] Next, samples for magnetic measurement were cut out from the obtained non-oriented electrical steel sheet, and iron loss W10 / 3000 at 3000 Hz and 1T and iron loss W10 / 800 at 800 Hz and 1T were measured. In addition, a sample for observation was cut out, and the cross section of the non-oriented electrical steel sheet was observed. As an observation method, SEM and GDS were used to measure the thickness of the Cr oxide layer. As a result, the thickness of the Cr oxide layer is sho...
Embodiment 2)
[0064] First, a hot-rolled sheet containing C: 0.002% by mass, S: 0.002% by mass, N: 0.002% by mass, and Mn: 0.3% by mass, Si, Al, and Cr as components A to L shown in Table 3 below was prepared. , pickled, and cold-rolled to obtain a cold-rolled sheet with a thickness of 0.15 mm to 0.30 mm. Next, finish annealing at 1000° C. was performed in a dry hydrogen atmosphere. The oxygen potential P at this time H2O / P H2 3×10 at 300-500°C during heating -4 , 1×10 in soaking -4 , to obtain a non-oriented electrical steel sheet.
[0065] table 3
[0066]
[0067] Next, samples for magnetic measurement were cut out from the obtained non-oriented electrical steel sheet, and iron loss W10 / 3000 at 3000 Hz and 1T, iron loss W10 / 800 at 800 Hz and 1T, and iron loss W10 / 400 at 400 Hz and 1T were measured. In addition, the thickness of the Cr oxide layer was measured in the same procedure as in Example 1. As a result, the thickness of the Cr oxide layer was in the range of 0.01 μm to 0...
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