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A kind of low-temperature foaming aid and preparation method thereof

A technology of low-temperature foaming agent and foaming auxiliary agent, which is applied in the field of low-temperature foaming agent and its preparation, can solve the problems of collapse or merger of PVC cells, slow degassing speed of decomposition, and lower production efficiency, so as to reduce the foaming rate of PVC. Bubble temperature, increase cell uniformity, and reduce the effect of usage

Inactive Publication Date: 2016-09-28
FOSHAN GAOMING JUNTENG PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, organic foaming agents include azo compounds, nitroso compounds, sulfonyl hydrazide compounds, azide compounds, diazo compounds, etc., which are prone to generate nitrogen and a small amount of carbon dioxide, carbon monoxide, ammonia and other gases under the action of heat to cause Foaming effect, has the advantages of narrow decomposition temperature range and good dispersion in polymers; but the disadvantage is high decomposition temperature and fast decomposition and degassing speed
Under high temperature, PVC accumulates a large amount of internal heat, resulting in local damage or even scorching of PVC foam, and the instantaneous generation of a large amount of gas will cause PVC cells to collapse or merge, seriously reducing the quality of PVC foam materials
Inorganic foaming agents include ammonium carbonate, ammonium bicarbonate, and sodium bicarbonate, etc., which easily generate carbon dioxide under the action of heat to cause foaming, and have the advantages of low cost, non-toxic, and low decomposition temperature; but the disadvantage is the speed of decomposition and degassing slow, reducing productivity

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A low-temperature foaming aid, comprising A and B two components, wherein A component contains the following components by weight: 175 parts of potassium chloride, 100 parts of borax, 200 parts of DOTP plasticizer, and B component contains the following Ingredients in weight fraction: 400 parts of zinc chloride, 100 parts of sodium bicarbonate, 40 parts of titanate coupling agent, and 300 parts of DOTP plasticizer.

[0020] The preparation method of the low-temperature foaming aid of the present invention is as follows: mix and soak the A component according to the proportion for 1 hour, and primary grind it for 8 hours at room temperature, then put the B component into the proportion according to the proportion and mix evenly, After fine grinding for 6 hours at room temperature, the product was obtained after fineness inspection.

Embodiment 2

[0022] A low-temperature foaming aid, comprising A and B two components, wherein the A component contains the following components by weight: 140 parts of potassium chloride, 80 parts of borax, 180 parts of DOTP plasticizer, and the B component contains the following Ingredients in weight fraction: 350 parts of zinc chloride, 80 parts of sodium bicarbonate, 35 parts of titanate coupling agent, and 280 parts of DOTP plasticizer.

[0023] The preparation method of the low-temperature foaming aid of the present invention is as follows: mix and soak the A component according to the proportion for 1 hour, and primary grind it for 8 hours at room temperature, then put the B component into the proportion according to the proportion and mix evenly, After fine grinding for 6 hours at room temperature, the product was obtained after fineness inspection.

Embodiment 3

[0025] A low-temperature foaming aid, comprising A and B two components, wherein the A component contains the following components by weight: 150 parts of potassium chloride, 100 parts of borax, 200 parts of DOTP plasticizer, and the B component contains the following Ingredients in weight fraction: 420 parts of zinc chloride, 90 parts of sodium bicarbonate, 40 parts of titanate coupling agent, and 300 parts of DOTP plasticizer.

[0026] The preparation method of the low-temperature foaming aid of the present invention is as follows: mix and soak the A component according to the proportion for 1 hour, and primary grind it for 8 hours at room temperature, then put the B component into the proportion according to the proportion and mix evenly, After fine grinding for 6 hours at room temperature, the product was obtained after fineness inspection.

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PUM

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Abstract

The invention provides a low temperature blowing promoter and a preparing method thereof. The low temperature blowing promoter comprises a component A and a component B, wherein by weight, the component A comprises 140 to 200 parts of potassium chloride, 80 to 120 parts of sodium borate and 180 to 250 parts of DOPT plasticizer, and the component B comprises 350 to 450 parts of zinc chloride, 80 to 120 parts of sodium bicarbonate, 35 to 50 parts of titanate coupling agents and 280 to 350 parts of DOPT plasticizer. The preparing method for the low temperature blowing promoter comprises the steps that the component A is mixed and steeped for one hour according to the proportions, and then primary grinding is carried out for eight hours; then, the component B is poured in and mixed evenly, then fine grinding is carried out for six hours at room temperature; and a product is obtained after fineness detection is carried out. The low temperature blowing promoter has the advantages of being good in dispersity and gentle in decomposition in the heat, effectively lowering PVC foaming temperature, increasing cell evenness, thickening bubble walls, reducing the using amount of the plasticizer and the like.

Description

technical field [0001] The invention relates to a foaming aid, in particular to a low-temperature foaming agent capable of reducing the foaming temperature of PVC and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC) foam material is a new type of material that has developed rapidly in recent years. It is usually coated or pasted on the surface of the fabric, then heated to make it plasticized, and rolled flattened or embossed. Get PVC faux leather. PVC artificial leather is similar to natural leather. It has the advantages of light texture, convenient processing, water resistance and wear resistance, etc. It is widely used in clothing, shoes and hats, bags, furniture, automotive interiors and other fields. [0003] PVC foam molding is divided into three processes: the formation of the bubble core, the expansion of the bubble core and the curing of the foam body. The expansion of the bubble nucleus has a decisive influence on the cells of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J9/08C08L27/06C08K13/02C08K5/12C08K3/08C08K3/16
Inventor 沈平曾铁球符文海
Owner FOSHAN GAOMING JUNTENG PLASTICS
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