Cationic water purifying agent and application of same in oilfield chemical flooding produced liquid

A water purifying agent and cation technology, applied in the field of cationic water purifying agent, quaternary ammonium cationic high-efficiency water purifying agent for oilfield chemical flooding produced fluid, can solve the problem of no purification effect, poor water purification effect, poor flocculation effect, etc. problem, to achieve good flocculation effect, improve flocculation efficiency and low cost

Active Publication Date: 2014-10-01
PETROCHINA CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In this regard, conventional inorganic flocculants such as polyaluminum chloride have poor flocculation effects; anionic or non-ionic polymer flocculants have poor or no purification effects; cationic polymer water purifiers integrate The advantages of conventional inorganic flocculants and organic flocculants are more efficient, but for ASP flooding, there are still disadvantages of high cost and large dosage
Among various cationic polymer flocculants, the polycondensate of epichlorohydrin and dimethylamine has the lowest overall cost, but its flocculation efficiency for chemical flooding production fluid needs to be improved, and the main disadvantage is that the required dosage is relatively small Big

Method used

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  • Cationic water purifying agent and application of same in oilfield chemical flooding produced liquid
  • Cationic water purifying agent and application of same in oilfield chemical flooding produced liquid

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Embodiment

[0027] This embodiment provides a cationic water purifying agent, which is prepared through the following steps:

[0028] Add 5.8g of dodecylamine, 9.5g of emulsifier OP-10 and 47g of epichlorohydrin into the reaction kettle, stir to dissolve, and raise the temperature to 80°C;

[0029] Take by weighing 4.2g hexamethylenetetramine, add about 25mL distilled water and make it dissolve, obtain the hexamethylenetetramine aqueous solution, then add 42g dimethylamine (content is 33wt%), pack into feeder after mixing, When the temperature of the reaction kettle is raised to 80°C, use the feeder to slowly drop the mixed solution into the reaction kettle, use the heat of reaction to raise the temperature of the reaction solution to 90°C, and adjust the dropping speed to maintain 90°C until the addition of the mixed solution in the feeder is completed;

[0030] Then, when the temperature of the reaction liquid is lowered to 70°C, add sulfuric acid to adjust the pH value of the reaction ...

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Abstract

The invention relates to a cationic water purifying agent and application of the same in an oilfield chemical flooding produced liquid. The cationic water purifying agent is prepared through the following steps: mixing dodecylamine, an emulsifier OP-10 and chloropropylene oxide, carrying out dissolving with stirring and then heating to 80 DEG C so as to obtain a mixed solution; adding a mixed liquor of an aqueous hexamethylene tetramine solution and dimethylamine into the mixed solution drop by drop; and after a reaction solution is cooled to 70 DEG C, adding acid to adjust the pH value of the reaction solution to 5, adding a catalyst, maintaining a temperature to be 70 DEG C, carrying out a reaction for 4 h and then cooling to room temperature so as to obtain the cationic water purifying agent. The invention further provides application of the cationic water purifying agent in purifying of an oilfield ternary composite flooding produced liquid. The cationic water purifying agent provided by the invention is a condensed type quaternary ammonium salt high polymer and has the advantages of a good flocculation effect, a small usage amount, low cost and a substantial purifying effect especially on the oilfield ternary composite flooding produced liquid.

Description

technical field [0001] The invention relates to a cationic water purifying agent and its application in oilfield chemical flooding production fluid, in particular to a quaternary ammonium cationic high-efficiency water purifying agent for oilfield chemical flooding production fluid and its application, belonging to the technical field of petrochemical industry . Background technique [0002] Oilfield chemical flooding production fluids include production fluids produced by chemical methods such as alkali flooding, active agent flooding, and polymer flooding for the purpose of enhancing oil recovery. [0003] Oilfield chemical flooding production fluid, especially ASP flooding production fluid is characterized by: high alkalinity, high content of polyacrylamide residual polymer, high content of surfactant, high content of suspended solids, high oil content, is A relatively stable oil-in-water negatively charged colloidal emulsion. Therefore, the purification treatment and r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/56C08G59/10
Inventor 苏慧敏马自俊
Owner PETROCHINA CO LTD
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