A kind of corn compound fertilizer and preparation method thereof
A compound fertilizer and compound fertilizer technology, applied in the direction of substrate fertilizer, fertilization device, fertilizer mixture, etc., can solve the problems of reduced water retention effect, limited water retention effect, complicated preparation process, etc., to improve strength and pelleting rate, reduce The effect of watering frequency and simple process
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[0041] Wherein, the preparation method of cyclodextrin superabsorbent resin of the present invention comprises the following steps:
[0042] a. Mix starch and cyclodextrin with water evenly, and add lye to gelatinize under the protection of inert gas;
[0043] b. Add lye dropwise to acrylic acid to neutralize to obtain acrylic acid / acrylic acid salt mixed solution;
[0044] c. Under the protection of an inert gas, mix the gelatinized starch obtained in step a, the acrylic acid / acrylate mixed solution obtained in step b, and the initiator evenly, raise the temperature to 50-55°C and keep it for 2 hours, add absolute ethanol to collect white viscous precipitation;
[0045] Wherein step a and step b are in no particular order.
[0046] The cyclodextrin superabsorbent resin of the present invention is obtained through the graft copolymerization reaction of starch and acrylic acid (sodium) monomer. That is, through the initiator, the hydrogen on the tertiary carbon of the starch...
Embodiment 1
[0092] Embodiment 1, the preparation of cyclodextrin superabsorbent resin of the present invention
[0093] 1. Add 10.0g of cornstarch and 0.1g of β-cyclodextrin into a 100ml four-neck flask, then add 40ml of distilled water, and start electric stirring at the same time;
[0094] 2. Take 20ml of distilled water, place it in a 50ml beaker, weigh 0.5g of sodium hydroxide into the beaker, shake the beaker gently to dissolve the sodium hydroxide completely, and prepare a sodium hydroxide solution with a concentration of 0.5mol / L. The solution was placed in a fume hood for cooling; the sodium hydroxide solution cooled to room temperature was slowly added to the four-necked flask under stirring, and the gelatinization of the starch was carried out; nitrogen protection was always passed during the process;
[0095] 3. Measure 22ml of distilled water, place it in a 50ml beaker, weigh 2.6g of sodium hydroxide into the beaker, shake the beaker gently to dissolve the sodium hydroxide com...
Embodiment 2
[0100] Embodiment 2, the preparation of corn compound fertilizer (N:P 2 o 5 :K 2 O=27:6:7)
[0101] 60% potassium chloride 115kg, 57% monoammonium phosphate 135kg, 46.2% urea 420kg, 23.5% ammonium chloride 200kg, ammonium sulfate 25kg, ammonium bicarbonate 30kg, composite trace element 30kg, bentonite (purchased from Henan) 45kg, embodiment 1. 30kg of the cyclodextrin superabsorbent resin prepared, wherein the compound trace element is composed of 15kg of amino acid zinc, 5kg of boric acid, 1kg of amino acid copper, 3kg of amino acid iron, and 6kg of fulvic acid.
[0102] Preparation method: Mix organic-inorganic compound fertilizer evenly with all ingredients except cyclodextrin superabsorbent resin; cyclodextrin superabsorbent resin is heated to 85°C in the storage tank and kept warm, and pumped to the granulator with a metering pump In the process, use compressed air to atomize and spray on the organic-inorganic compound fertilizer, rotate and granulate, and the granulat...
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Abstract
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