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Spray-free thermosetting resin composition with special aesthetic effect and its preparation method and application

A technology of resin composition and special effect powder, which is applied in the field of spray-free thermosetting resin composition and its preparation, can solve the problems of uneven distribution of special effect powder, unstable flow rate, flow marks and weld lines, etc., and improve market application range, improved shear resistance, and the effect of reducing weld lines

Active Publication Date: 2017-11-17
KINGFA SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

By dispersing the special effect powder into the matrix resin, the special effect powder is connected to each other to form a continuous special effect film, which covers the base material and presents a special effect texture, although the special effect powder is directly added to the resin base. , can achieve a special glossy effect, but the compatibility between the matrix resin and the special effect powder is poor. Under the strong pressure and strong shear conditions of extrusion or injection molding, it is difficult for the special effect powder and the matrix resin material to achieve the same fluidity, especially It is a product with a complex structure. The special effect powder oriented along the flow direction occurs and the melt flow turns, the flow velocity is unstable, and the melt merges, etc., causing the special effect powder to be unevenly distributed in the melt and easy to form on the surface of the product. Defects such as flow marks and weld lines seriously prevent and limit the market promotion and application of this type of spray-free material

Method used

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  • Spray-free thermosetting resin composition with special aesthetic effect and its preparation method and application
  • Spray-free thermosetting resin composition with special aesthetic effect and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-6

[0044] Example 1-6 Preparation of polymer-coated special effect powder microspheres:

[0045]According to the formula in Table 1, firstly, add anti-oxidation and corrosion inhibitor to the water-based polymer dispersion at room temperature, stir and disperse for 15 minutes to obtain a dispersion; while stirring, slowly add special effect powder, or water-based Special effect powder slurry, then add curing agent while stirring, and continue to stir for 30-120 minutes, so that the special effect powder is fully dispersed and covered by the dispersion liquid, and finally a composite dispersion liquid of polymer-coated special effect powder is obtained; The composite dispersion liquid is spray-dried to obtain polymer-coated special-effect powder microspheres. The temperature of the air inlet during the spray-drying process is 150-300° C., and the temperature of the air outlet is 50-130° C.

Embodiment 1

[0048] In Example 1: the water-based polymer dispersion is a polyurethane emulsion, and its solid content is 10wt%; the metal powder is a surface-treated flake aluminum powder, and the content of the Al element in the aluminum powder is 60wt%, containing Zn and Sn at the same time; The particle size is 100μm; the anti-oxidation and corrosion inhibitor is pyrogallic acid; the curing agent is polyisocyanate.

Embodiment 2

[0049] In embodiment 2: the aqueous polymer dispersion liquid is polyacrylate emulsion, and its solid content is 30wt%; Metal powder is the flaky copper powder through surface treatment, and the content of Cu element is 70wt% in the copper powder, contains Zn and Sn; its particle size is 5 μm; the anti-oxidant corrosion inhibitor is benzotriazole; the curing agent is polycarbodiimide.

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Abstract

The invention discloses a spraying-free thermosetting resin composition having special aesthetic effects and a preparation method and an application thereof. The spraying-free thermosetting resin composition comprises the following components: 70-98 wt% of thermosetting resin, 1-25 wt% of microspheres formed by coating a special-effect powder with a polymer, 0-10 wt% of a compatibilizer, 0.1-1 wt% of an antioxidant, and 0.1-0.5 wt% of a processing auxiliary agent. The special-effect powder is coated with a water-based polymer dispersion liquid to form the microspheres, and then the microspheres are dispersed to the thermosetting resin, so that the compatibility of the special-effect powder and the thermosetting resin can be significantly improved, flow marks formed on the surface of products in an extrusion or injection molding process are eliminated, and weld lines are reduced; and the prepared spraying-free thermosetting resin composition has relatively obvious metal texture, pearly flashing effects and other special aesthetic effects, and the market application range of spraying-free materials is greatly improved.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a spray-free thermosetting resin composition with special aesthetic effects, a preparation method and application thereof. Background technique [0002] As people pay more and more attention to environmental issues, spray-free material products are gradually showing their competitiveness. Spray-free aesthetic resins can replicate the bright and colorful hues produced by spray paint, pearlescent, glitter effects, metallic luster and texture, etc. Special effects, so as to meet diversified and differentiated customer needs, and can truly achieve energy saving and emission reduction in the production process, and can be widely used in electronic appliances, vehicles and ships, chemicals, machinery, construction, sports, daily necessities and other fields. [0003] At present, the more common preparation method of spray-free resin is to add metal powder, pearl powder and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L63/00C08L61/06C08L61/24C08L61/28C08L33/04C08L75/04C08L83/00C08L79/08C08K13/06C08K9/10C08K3/08
Inventor 陈平绪叶南飚胡纲宁方林孙雅杰宋晓辉王大中
Owner KINGFA SCI & TECH CO LTD
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