A kind of anti-glue paint protective film and preparation method thereof
A protective film and glue breaking technology, which is applied in the direction of adhesives, pressure-sensitive films/sheets, film/sheet-shaped adhesives, etc., can solve problems affecting the adhesion and transparency of the film, and achieve good tensile fracture, The effect of resistance to tensile fracture
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Embodiment 1
[0031] A preparation method for an anti-glue-breaking paint surface protective film, comprising the following steps:
[0032] 1) Preparation of anti-broken pressure-sensitive adhesive
[0033] a, the preparation of functional monomer polytetrahydrofuryl acrylate;
[0034] Polytetrahydrofuran ether diol with a number average molecular weight of 600 is dissolved in dichloromethane, and the concentration of polytetrahydrofuran ether diol dissolved in dichloromethane is 20wt%, and then added dropwise to acrylic acid chloride for reaction, polytetrahydrofuran ether diol The molar ratio of ether diol to acrylic acid chloride is 1:1, the reaction temperature is 10°C, and the reaction time is 2 hours. During the reaction, triethylamine is used to absorb the hydrogen chloride gas generated during the reaction. The molar ratio of triethylamine to acrylic acid chloride The ratio is 1:1; the reaction product is separated by extraction, vacuum distillation and vacuum drying to generate po...
Embodiment 2
[0044] A preparation method for an anti-glue-breaking paint surface protective film, comprising the following steps:
[0045] 1) Preparation of anti-broken pressure-sensitive adhesive
[0046] a, the preparation of functional monomer polytetrahydrofuryl acrylate;
[0047] Polytetrahydrofuran ether diol with a number average molecular weight of 2000 is dissolved in dichloromethane, and the concentration of polytetrahydrofuran ether diol dissolved in dichloromethane is 30wt%, and then added dropwise to acrylic acid chloride for reaction, polytetrahydrofuran ether The molar ratio of ether diol to acrylic acid chloride is 1.3:1, the reaction temperature is 30°C, and the reaction time is 3h. During the reaction, triethylamine is used to absorb the hydrogen chloride gas generated during the reaction. The molar ratio of triethylamine to acrylic acid chloride The ratio is 1:1; the reaction product is separated by extraction, vacuum distillation and vacuum drying to generate polytetra...
Embodiment 3
[0057] A preparation method for an anti-glue-breaking paint surface protective film, comprising the following steps:
[0058] 1) Preparation of anti-broken pressure-sensitive adhesive
[0059] a, the preparation of functional monomer polytetrahydrofuryl acrylate;
[0060] The polytetrahydrofuran ether diol that the number average molecular weight is 1000 is dissolved in methylene chloride, and the concentration that polytetrahydrofuran ether diol is dissolved in methylene chloride is 25wt%, is then added dropwise in the reaction of acrylic acid chloride, polytetrahydrofuran ether The molar ratio of ether diol to acrylic acid chloride is 1.1:1, the reaction temperature is 15°C, and the reaction time is 2.5h. During the reaction, triethylamine is used to absorb the hydrogen chloride gas generated during the reaction. The moles of triethylamine and acrylic acid chloride The ratio is 1:1; the reaction product is separated by extraction, vacuum distillation and vacuum drying to ge...
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