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A kind of phosphogypsum substrate imitation wood floor and preparation method thereof

一种仿木地板、磷石膏的技术,应用在建筑材料领域,能够解决降低早期强度、生产流程长、胶凝性、含水量高等问题,达到提高强度和耐水性、增强凝固性能、增强综合性能的效果

Inactive Publication Date: 2017-07-25
GUIZHOU KAILIN PHOSPHOGYPSUM INTEGRATION UTILIZATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The crystal form of phosphogypsum is the same as that of natural gypsum, which is a prismatic or columnar plate crystal, and its chemical composition is basically similar to that of natural gypsum. Phosphorus and organic impurities will prolong the hydration time of cement, reduce the early strength and prolong the setting time, so phosphogypsum cannot be directly used as a retarder for cement
Phosphogypsum needs to be processed. The current common method is to process phosphogypsum through washing, pretreatment, drying and calcination. This method is low in cost to obtain cement retarder, but the process of producing cement retarder from phosphogypsum is long. , the equipment investment is large, and the flocculant still inevitably contains phosphorus pentoxide and fluoride, which makes the hydration time and coagulation time of cement longer
[0005] The third method: making ammonium sulfate and calcium carbonate from phosphogypsum. This method uses ammonia and carbon dioxide to convert phosphogypsum into ammonium sulfate and calcium carbonate. Big
At present, phosphogypsum is usually mixed with a small amount of cement, pulp, fiber reinforced materials, etc., and then pressurized to make phosphogypsum fiberboard. Because phosphogypsum itself does not have gelling properties, high water content, and contains various impurities, etc. , the phosphogypsum phosphogypsum base imitation wood floor produced by this method has low wear resistance, weather resistance, compressive strength and other properties, and it is difficult to meet the use requirements of building decoration materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] raw material:

[0040] Phosphogypsum 50kg, fly ash 10kg, fiber 0.5kg, yellow phosphorus slag 20kg and quicklime 2kg.

[0041] Preparation:

[0042] The yellow phosphorus slag was ball-milled into 80-mesh fine powder at a temperature of 40°C to obtain slag powder, and the phosphogypsum, fly ash, fiber, slag powder and quicklime were stirred and reacted at a temperature of 50°C for 3 hours, and the obtained mixed material was naturally Aging treatment for 16 days, adding 10% water of the weight of the mixed material to the aged mixed material, stirring evenly, pouring into the mold, obtaining the formed phosphogypsum base material after demoulding, sending the phosphogypsum base material into Curing treatment in a curing room at normal pressure and steam temperature of 95°C for 20 hours, slowly drying the cured phosphogypsum base material at a temperature of 40°C until the moisture content is 3%, and then sanding it smooth with 240# sandpaper, Make it evenness 0.5mm, th...

Embodiment 2

[0044] raw material:

[0045] Phosphogypsum 70kg, fly ash 18kg, fiber 3kg, yellow phosphorus slag 30kg and quicklime 6kg.

[0046] Preparation:

[0047] Ball mill the yellow phosphorus slag into 100-mesh fine powder at a temperature of 60°C to obtain slag powder, stir and react phosphogypsum, fly ash, fiber, slag powder and quicklime at a temperature of 60°C for 4 hours, and make the obtained mixture naturally Aging treatment for 24 days, adding water with 15% weight of the mixed material to the aged mixed material, stirring evenly, pouring into the mold, obtaining the formed phosphogypsum base material after demoulding, sending the phosphogypsum base material into Curing treatment in a curing room at normal pressure and steam temperature of 105°C for 16 hours, slowly drying the cured phosphogypsum base material at a temperature of 60°C until the moisture content is 3%, and then smoothing it with 240# sandpaper, Make it evenness 3mm, then spray nitro wood grain primer with a...

Embodiment 3

[0049] raw material:

[0050] Phosphogypsum 55kg, fly ash 12kg, fiber 1kg, yellow phosphorus slag 22kg and quicklime 3kg.

[0051] Preparation:

[0052] The yellow phosphorus slag was ball-milled into 100-mesh fine powder at a temperature of 45°C to obtain slag powder, and the phosphogypsum, fly ash, fiber, slag powder and quicklime were stirred and reacted at a temperature of 52°C for 3.2 hours, and the obtained mixed material was Naturally aging for 17 days, adding water with 11% weight of the mixed material to the aged mixed material and stirring evenly, pouring it into a mold, obtaining a formed phosphogypsum base material after demoulding, sending the phosphogypsum base material to Put it into a curing room with normal pressure and a steam temperature of 98°C for 17 hours, slowly dry the cured phosphogypsum base material at a temperature of 45°C until the moisture content is 6%, and then sand it smooth with 240# sandpaper , so that the flatness is 2.5mm, and then spray ...

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Abstract

The invention discloses a phosphogypsum substrate simulated wood floor and a preparation method thereof. The phosphogypsum substrate simulated wood floor is prepared from the following raw materials in parts by weight: 50-70 parts of phosphogypsum, 10-18 parts of flyash, 0.5-3 parts of fiber, 20-30 parts of yellow phosphorus slag and 2-6 parts of quick lime. The phosphogypsum substrate simulated wood floor is prepared by taking the phosphogypsum as the main raw material, solves the current situation that the phosphogypsum is piled up like a mountain and has an important meaning for the environment protection and the sustainable development. Besides, the produced phosphogypsum substrate simulated wood floor has the advantages of light weight, good waterproof and fireproof performances, high compressive strength and strong weather fastness and can be widely used as an indoor and outdoor decorative material.

Description

technical field [0001] The invention relates to the technical field of building materials, in particular to a phosphogypsum base material imitation wood floor and a preparation method thereof. Background technique [0002] In the phosphoric acid production process, every ton of P produced 2 o 5 Five tons of phosphogypsum are produced by-product, and the annual by-production of phosphogypsum by medium-sized phosphoric acid production enterprises is about 3.5 million tons. So much phosphogypsum not only requires a large slag dump, but also causes water pollution. At present, the most commonly used phosphogypsum treatment methods are as follows: [0003] The first method: Phosphoric acid paste is used to backfill the pit. According to statistics, when phosphogypsum is not used to backfill the mine shaft, the filling cost of the mine shaft accounts for 1 / 3 of the mining, and the filling material accounts for 80% of the filling cost. If phosphogypsum is used to fill the mine ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/14C04B18/30C04B41/71B28B11/24
CPCY02W30/91
Inventor 向前勇杨永彬杨步雷王伟刘小成胡新菊李泽钢
Owner GUIZHOU KAILIN PHOSPHOGYPSUM INTEGRATION UTILIZATION
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