Nonaqueous electrolyte secondary battery
A non-aqueous electrolyte and secondary battery technology, applied in the direction of non-aqueous electrolyte batteries, non-aqueous electrolyte battery electrodes, secondary batteries, etc., can solve the problems of cycle characteristics deterioration and area increase of non-aqueous electrolyte secondary batteries, and achieve the goal of suppressing Effect of Deterioration of Cycle Characteristics
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Embodiment 1
[0035] The non-aqueous electrolyte secondary battery according to the embodiment of the present invention will be described in further detail by giving specific examples. In Examples, a positive electrode plate having a 200 mm×220 mm main surface of the positive electrode active material layer facing the negative electrode was used. In addition, a negative electrode plate having a main surface of the negative electrode active material layer facing the positive electrode of 204 mm×224 mm larger than the main surface of the positive electrode active material layer was used.
[0036] Manufacture of positive plate
[0037] As the first positive electrode active material, Li with spinel structure 1.1 mn 1.9 o 4 powder, lithium-nickel-cobalt-lithium manganate (the molar ratio of Ni / Li is 0.7) as the second positive electrode active material, polyvinylidene fluoride as the binder resin, and carbon black powder as the conductive additive, The positive electrode slurry was prepared...
Embodiment 2
[0050] Except that the first positive electrode active material, the second positive electrode active material, the binder resin, and the conduction aid were mixed according to the ratio of solid component mass ratio 70:23:3:4, it was made in the same manner as in Example 1. secondary battery. The binder content of the positive electrode active material layer was 3% by mass. Adhesive adhesion amount area ratio is 12mg / m 2 .
Embodiment 3
[0052] Except that the first positive electrode active material, the second positive electrode active material, the binder resin, and the conduction aid were mixed according to the ratio of solid component mass ratio 69.5:23:3.5:4, it was made in the same manner as in Example 1. secondary battery. The content of the binder relative to the mass of the positive electrode active material layer was 3.5% by mass. Adhesive adhesion amount area ratio is 14mg / m 2 .
[0053] As mentioned above, the examples of the embodiments of the present invention have been described, but the above-mentioned examples are merely examples of the embodiments of the present invention, and do not mean that the technical scope of the embodiments of the present invention is limited to the above-mentioned examples. Concrete constitution of embodiment.
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Abstract
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